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They appear in the Butler–Volmer equation and related expressions. The symmetry factor and the charge transfer coefficient are dimensionless. [1] According to an IUPAC definition, [2] for a reaction with a single rate-determining step, the charge transfer coefficient for a cathodic reaction (the cathodic transfer coefficient, α c) is defined as:
There are two rates which determine the current-voltage relationship for an electrode. First is the rate of the chemical reaction at the electrode, which consumes reactants and produces products. This is known as the charge transfer rate. The second is the rate at which reactants are provided, and products removed, from the electrode region by ...
The adenylate energy charge is an index used to measure the energy status of biological cells.. ATP or Mg-ATP is the principal molecule for storing and transferring energy in the cell : it is used for biosynthetic pathways, maintenance of transmembrane gradients, movement, cell division, etc...
This is the energy (i.e. work) per charge which is required to move a (very small) positive charge at constant velocity across the cell membrane from the exterior to the interior. (If the charge is allowed to change velocity, the change of kinetic energy and production of radiation [ 1 ] must be taken into account.)
The allowed cell rate is the rate in cells per second at which a source device may send data in ATM networks. It is bounded by the minimum cell rate and the peak cell rate . [ 1 ]
Such rates provide insights into the structure and bonding in the analyte and the electrode. For example, the exchange current densities for platinum and mercury electrodes for reduction of protons differ by a factor of 10 10 , indicative of the excellent catalytic properties of platinum.
The charge control consists of a pressure switch built into the cell, which disconnects the charging current when the internal cell pressure rises above a certain limit; usually 200 pounds per square inch (1.4 MPa) to 300 pounds per square inch (2.1 MPa). This prevents overcharging and damage to the cell.
Intuitively one may understand these limits as follows: if an ion is only found outside a cell, then the flux is Ohmic (proportional to voltage) when the voltage causes the ion to flow into the cell, but no voltage could cause the ion to flow out of the cell, since there are no ions inside the cell in the first place.