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Scientific laws or laws of science are statements, based on repeated experiments or observations, that describe or predict a range of natural phenomena. [1] The term law has diverse usage in many cases (approximate, accurate, broad, or narrow) across all fields of natural science (physics, chemistry, astronomy, geoscience, biology).
Le Chatelier–Braun principle analyzes the qualitative behaviour of a thermodynamic system when a particular one of its externally controlled state variables, say , changes by an amount , the 'driving change', causing a change , the 'response of prime interest', in its conjugate state variable , all other externally controlled state variables remaining constant.
Bragg's Law: Physics William Lawrence Bragg, William Henry Bragg: Bradford's law: Computer science: Samuel C. Bradford: Bruun Rule: Earth science Per Bruun Buys Ballot's law: Meteorology: C.H.D. Buys Ballot: Byerlee's law: Geophysics: James Byerlee: Carnot's theorem: Thermodynamics: Nicolas Léonard Sadi Carnot: Cauchy's integral formula Cauchy ...
This is the most useful form of the second law of thermodynamics in chemistry, where free-energy changes can be calculated from tabulated enthalpies of formation and standard molar entropies of reactants and products. [19] [15] The chemical equilibrium condition at constant T and p without electrical work is dG = 0.
According to van der Waals, the theorem of corresponding states (or principle/law of corresponding states) indicates that all fluids, when compared at the same reduced temperature and reduced pressure, have approximately the same compressibility factor and all deviate from ideal gas behavior to about the same degree. [1] [2]
Traité élémentaire de chimie [1] is a textbook written by Antoine Lavoisier published in 1789 and translated into English by Robert Kerr in 1790 under the title Elements of Chemistry in a New Systematic Order containing All the Modern Discoveries. [2] It is considered to be the first modern chemical textbook. [3]
In chemistry, the calculation of the amount of reactant and products in a chemical reaction, or stoichiometry, is founded on the principle of conservation of mass. The principle implies that during a chemical reaction the total mass of the reactants is equal to the total mass of the products. For example, in the following reaction
The concepts of Hess's law can be expanded to include changes in entropy and in Gibbs free energy, since these are also state functions. The Bordwell thermodynamic cycle is an example of such an extension that takes advantage of easily measured equilibria and redox potentials to determine experimentally inaccessible Gibbs free energy values.