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Calomel is a mercury chloride mineral with formula Hg 2 Cl 2 (see mercury(I) chloride). It was used as a medicine from the 16th to early 20th century, despite frequently causing mercury poisoning in patients. [5] The name derives from Greek kalos (beautiful) and melas (black) because it turns black on reaction with ammonia. This was known to ...
Mercury(I) chloride is the chemical compound with the formula Hg 2 Cl 2. Also known as the mineral calomel [4] (a rare mineral) or mercurous chloride, this dense white or yellowish-white, odorless solid is the principal example of a mercury(I) compound. It is a component of reference electrodes in electrochemistry. [5] [6]
The aqueous phase in contact with the mercury and the mercury(I) chloride (Hg 2 Cl 2, "calomel") is a saturated solution of potassium chloride in water. The electrode is normally linked via a porous frit (sometimes coupled to a salt bridge ) to the solution in which the other electrode is immersed.
The silver chloride electrode is most commonly used as a reference electrode in pH meters, although some designs use the saturated calomel electrode. The silver chloride electrode is simple to manufacture and provides high reproducibility. The reference electrode usually consists of a platinum wire that has contact with a silver/silver chloride ...
Mercury poisoning is a type of metal poisoning due to exposure to mercury. [3] Symptoms depend upon the type, dose, method, and duration of exposure. [3] [4] They may include muscle weakness, poor coordination, numbness in the hands and feet, skin rashes, anxiety, memory problems, trouble speaking, trouble hearing, or trouble seeing. [1]
It was also used for scaling in psoriasis, to treat pruritus ani, and against pinworm and ringworm infection (especially in dogs), against crab louse infestation, [7] against lesions on the body and near eyes, against bumblefoot infection on poultry, and as a disinfectant. [11] [13] Chronic use of this medication can lead to systemic mercury ...
Heyrovský's Polarograph. Polarography is an electrochemical voltammetric technique that employs (dropping or static) mercury drop as a working electrode. In its most simple form polarography can be used to determine concentrations of electroactive species in liquids by measuring their mass-transport limiting currents.
If potassium chloride is added to mercurous nitrate on one side, mercury (I) chloride is precipitated. This decreased the osmotic pressure of mercury (I) ions on the side and creates a potential difference. This potential difference increases slowly as additional potassium chloride is added, but then increases more rapidly.