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This limits the usefulness of austenitic stainless steel for containing water with higher than a few parts per million content of chlorides at temperatures above 50 °C (122 °F); mild steel cracks in the presence of alkali (e.g. boiler cracking and caustic stress corrosion cracking) and nitrates;
Tempering is most often performed on steel that has been heated above its upper critical (A 3) temperature and then quickly cooled, in a process called quenching, using methods such as immersing the hot steel in water, oil, or forced-air. The quenched steel, being placed in or very near its hardest possible state, is then tempered to ...
Stainless steel can pose special corrosion challenges, since its passivating behavior relies on the presence of a major alloying component (chromium, at least 11.5%). Because of the elevated temperatures of welding and heat treatment, chromium carbides can form in the grain boundaries of stainless alloys. This chemical reaction robs the ...
Lead can form a low-melting slag capable of fluxing protective oxide scales. [7] [8] Lead is more often known for causing stress corrosion cracking in common materials that are exposed to molten lead. The cracking tendency of lead has been known for some time, since most iron based alloys, including those used in steel containers and vessels ...
Improper use of aluminium in contact with stainless steel had caused rapid corrosion in the presence of salt water. [13] The electrochemical potential difference between stainless steel and aluminium is in the range of 0.5 to 1.0 V, depending on the exact alloys involved, and can cause considerable corrosion within months under unfavorable ...
One common mode of corrosion in corrosion-resistant steels is when small spots on the surface begin to rust because grain boundaries or embedded bits of foreign matter (such as grinding swarf) allow water molecules to oxidize some of the iron in those spots despite the alloying chromium. This is called rouging. Some grades of stainless steel ...
Rust scale forming and flaking off from a steel bar heated to its forging temperature of 1200°C. Rapid oxidation occurs when heated steel is exposed to air. Rust is a general name for a complex of oxides and hydroxides of iron, [4] which occur when iron or some alloys that contain iron are exposed to oxygen and moisture for a long period of ...
The 2014 Flint water crisis was caused by a combination of source water change and a lack of corrosion control. The new, higher-CSMR water not only dissolved lead and iron from the pipes themselves, but also broke up previous layers of lead-containing rusty scale in pipes, allowing them to enter the water supply. [8]
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