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A homologous series is a group of compounds that differ by a constant unit, generally a methylene (−CH 2 −) group. The reactants undergo a homologation when the number of a repeated structural unit in the molecules is increased. The most common homologation reactions increase the number of methylene (−CH 2 −) units in saturated chain ...
The name "homologous series" is also often used for any collection of compounds that have similar structures or include the same functional group, such as the general alkanes (straight and branched), the alkenes (olefins), the carbohydrates, etc. However, if the members cannot be arranged in a linear order by a single parameter, the collection ...
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Alkyl groups form homologous series. The simplest series have the general formula −C n H 2n+1. Alkyls include methyl, (−CH 3), ethyl (−C 2 H 5), propyl (−C 3 H 7), butyl (−C 4 H 9), pentyl (−C 5 H 11), and so on. Alkyl groups that contain one ring have the formula −C n H 2n−1, e.g. cyclopropyl and cyclohexyl.
There are several functional groups that contain an alkene such as vinyl group, allyl group, or acrylic group. Hydrocarbons may form charged structures: positively charged carbocations or negative carbanions. Carbocations are often named -um. Examples are tropylium and triphenylmethyl cations and the cyclopentadienyl anion.
The peak corresponding to the molecular ion is often, but not always, the base peak. Identification of the molecular ion can be difficult. Examining organic compounds, the relative intensity of the molecular ion peak diminishes with branching and with increasing mass in a homologous series.
If bonded to H it is an alcohol. The term alkoxide refers to the anionic conjugate bases of alcohols ( RO − ) or to ionic compounds containing such an anion. Alkoxide compounds are derivatives of alcohols where the hydrogen of the –OH group is replaced by a metal ; [ 2 ] for example, the sodium salt of ethanol ( CH 3 CH 2 OH ) is sodium ...
The C-N distance in isocyanides is 115.8 pm in methyl isocyanide.The C-N-C angles are near 180°. [3]Akin to carbon monoxide, isocyanides are described by two resonance structures, one with a triple bond between the nitrogen and the carbon and one with a double bond between.