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It is now apparent why Rydberg atoms have such peculiar properties: the radius of the orbit scales as n 2 (the n = 137 state of hydrogen has an atomic radius ~1 μm) and the geometric cross-section as n 4. Thus, Rydberg atoms are extremely large, with loosely bound valence electrons, easily perturbed or ionized by collisions or external fields.
Rydberg states have energies converging on the energy of the ion. The ionization energy threshold is the energy required to completely liberate an electron from the ionic core of an atom or molecule. In practice, a Rydberg wave packet is created by a laser pulse on a hydrogenic atom and thus populates a superposition of Rydberg states. [3]
The Rydberg constant is known to seven parts in a trillion. The mass of the electron relative to that of caesium and rubidium atoms is also known with extremely high precision. If the mass of the electron can be measured with sufficiently high precision, then α can be found from the Rydberg constant according to
Atoms that have been excited to very large principal quantum number are known as Rydberg atoms. These highly excited atoms have several desirable properties including high decay life-time and amplified couplings with electromagnetic fields. [19] The basic principle for Rydberg mediated gates is called the Rydberg blockade. [20]
Rydberg matter [1] is an exotic phase of matter formed by Rydberg atoms; it was predicted around 1980 by É. A. Manykin, M. I. Ozhovan and P. P. Poluéktov. [2] [3] It has been formed from various elements like caesium, [4] potassium, [5] hydrogen [6] [7] and nitrogen; [8] studies have been conducted on theoretical possibilities like sodium, beryllium, magnesium and calcium. [9]
These "near threshold Rydberg states" can have long lifetimes, particularly for the higher orbital angular momentum states that do not interact strongly with the ionic core. Rydberg molecules can condense to form clusters of Rydberg matter which has an extended lifetime against de-excitation. Dihelium (He 2 *) was the first known Rydberg ...
However, it can be possible to span this ionization threshold energy if the photon energy is resonant with an intermediate electronically excited state. While it is often possible to observe the lower Rydberg levels in conventional spectroscopy of atoms and small molecules, Rydberg states are even more important in laser ionization experiments ...
The hydrogen spectral series can be expressed simply in terms of the Rydberg constant for hydrogen and the Rydberg formula. In atomic physics , Rydberg unit of energy , symbol Ry, corresponds to the energy of the photon whose wavenumber is the Rydberg constant, i.e. the ionization energy of the hydrogen atom in a simplified Bohr model.