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Toggle the table of contents. ... Print/export Download as PDF ... Wikidata item; Appearance. move to sidebar hide. Solvent Density (g cm-3) Boiling point (°C) K b ...
Chromatographic peak resolution is given by = + where t R is the retention time and w b is the peak width at baseline. The bigger the time-difference and/or the smaller the bandwidths, the better the resolution of the compounds.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
In gas chromatography, the Kovats retention index (shorter Kovats index, retention index; plural retention indices) is used to convert retention times into system-independent constants. The index is named after the Hungarian-born Swiss chemist Ervin Kováts , who outlined the concept in the 1950s while performing research into the composition ...
An R F value will always be in the range 0 to 1; if the substance moves, it can only move in the direction of the solvent flow, and cannot move faster than the solvent. For example, if particular substance in an unknown mixture travels 2.5 cm and the solvent front travels 5.0 cm, the retardation factor would be 0.50.
The resulting chromatogram is therefore a weight distribution of the polymer as a function of retention volume. GPC chromatogram; V o = no retention, V t = complete retention, A and B = partial retention. The most sensitive detector is the differential UV photometer and the most common detector is the differential refractometer (DRI).
Organic Solvent or Inorganic Salt T (°C) Notes Dry ice: p-Xylene +13 [1] Dry ice: p-Dioxane +12 Dry ice: Cyclohexane +6 Dry ice: Benzene +5 Dry ice: Formamide +2 Ice: Water: 0 Ice: Ammonium chloride-5 0.3 to 1 ratio of salt to ice. Liquid N 2: Aniline-6 Ice: Sodium thiosulfate pentahydrate-8 1.1 to 1 ratio of salt to ice. Ice: Calcium chloride ...
Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for separating and analyzing compounds that can be vaporized without decomposition. Typical uses of GC include testing the purity of a particular substance, or separating the different components of a mixture. [ 1 ]