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A homologous series is a group of compounds that differ by a constant unit, generally a methylene (−CH 2 −) group. The reactants undergo a homologation when the number of a repeated structural unit in the molecules is increased. The most common homologation reactions increase the number of methylene (−CH 2 −) units in saturated chain ...
A homologue (also spelled as homolog) is a compound belonging to a homologous series. [1] Compounds within a homologous series typically have a fixed set of functional groups that gives them similar chemical and physical properties. (For example, the series of primary straight-chained alcohols has a hydroxyl at the end of the carbon chain ...
Alkyl groups form homologous series. The simplest series have the general formula −C n H 2n+1. Alkyls include methyl, (−CH 3), ethyl (−C 2 H 5), propyl (−C 3 H 7), butyl (−C 4 H 9), pentyl (−C 5 H 11), and so on. Alkyl groups that contain one ring have the formula −C n H 2n−1, e.g. cyclopropyl and cyclohexyl.
Acyclic alkenes, with only one double bond and no other functional groups (also known as mono-enes) form a homologous series of hydrocarbons with the general formula C n H 2n with n being a >1 natural number (which is two hydrogens less than the corresponding alkane).
Formation of a secondary alcohol via alkene reduction and hydration is shown: The hydroboration-oxidation and oxymercuration-reduction of alkenes are more reliable in organic synthesis. Alkenes react with N-bromosuccinimide and water in halohydrin formation reaction. Amines can be converted to diazonium salts, which are then hydrolyzed.
There are several functional groups that contain an alkene such as vinyl group, allyl group, or acrylic group. Hydrocarbons may form charged structures: positively charged carbocations or negative carbanions. Carbocations are often named -um. Examples are tropylium and triphenylmethyl cations and the cyclopentadienyl anion.
The term enol is an abbreviation of alkenol, a portmanteau deriving from "-ene"/"alkene" and the "-ol". Many kinds of enols are known. [1] Keto–enol tautomerism refers to a chemical equilibrium between a "keto" form (a carbonyl, named for the common ketone case) and an enol.
When the carbonyl is an aldehyde (R"=H), a rearrangement can occur to generate enone, although the secondary propargylic alcohol can be isolated in some cases. [2] When this rearrangement is catalyzed by an acid, it is called Meyer–Schuster rearrangement. When the base is sodium metal the reaction is called Nef synthesis.