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Electronegativity is not a uniquely defined property and may depend on the definition. The suggested values are all taken from WebElements as a consistent set. Many of the highly radioactive elements have values that must be predictions or extrapolations, but are unfortunately not marked as such.
It is to be expected that the electronegativity of an element will vary with its chemical environment, [7] but it is usually considered to be a transferable property, that is to say that similar values will be valid in a variety of situations. Caesium is the least electronegative element (0.79); fluorine is the most (3.98).
Fluorine is very difficult to form oxoacids with, due to the fact that it will take a lot of energy per mole to join each additional oxygen atom to fluorine owing to its exceptional electronegativity. The only known oxoacid of fluorine is hypofluorous acid (HOF). It appears as a white-solid below temperatures of -117°C, and a pale-yellow ...
The high electronegativity of fluorine (4.0 for fluorine vs. 2.5 for carbon) gives the carbon–fluorine bond a significant polarity or dipole moment. The electron density is concentrated around the fluorine, leaving the carbon relatively electron poor. This introduces ionic character to the bond through partial charges (C δ+ —F δ−). The ...
It also has a high electron affinity, second only to chlorine, [17] and tends to capture an electron to become isoelectronic with the noble gas neon; [3] it has the highest electronegativity of any reactive element. [18] Fluorine atoms have a small covalent radius of around 60 picometers, similar to those of its period neighbors oxygen and neon.
Fluorine is the thirteenth most abundant element on Earth and the 24th most abundant element in the universe. It is the most electronegative element and it is highly reactive. Thus, it is rarely found in its elemental state, although elemental fluorine has been identified in certain geochemical contexts. [3]
Xenon can be directly bonded to a less electronegative element than fluorine or oxygen, particularly carbon. [22] Electron-withdrawing groups, such as groups with fluorine substitution, are necessary to stabilize these compounds. [16] Numerous such compounds have been characterized, including: [17] [23] C 6 F 5 –Xe + –N≡C–CH
According to this scale, fluorine is the most electronegative element, while cesium is the least electronegative element. [17] Trend-wise, as one moves from left to right across a period in the modern periodic table, the electronegativity increases as the nuclear charge increases and the atomic size decreases.