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Matter organizes into various phases or states of matter depending on its constituents and external factors like pressure and temperature. Except at extreme temperatures and pressures, atoms form the three classical states of matter: solid , liquid and gas .
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
The three common states of matter. Along with oxidane, water is one of the two official names for the chemical compound H 2 O; [50] it is also the liquid phase of H 2 O. [51] The other two common states of matter of water are the solid phase, ice, and the gaseous phase, water vapor or steam.
The term phase is sometimes used as a synonym for state of matter, but it is possible for a single compound to form different phases that are in the same state of matter. For example, ice is the solid state of water, but there are multiple phases of ice with different crystal structures, which are formed at different pressures and temperatures.
At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the critical point. The critical point of water occurs at 647.096 K (373.946 °C; 705.103 °F) and 22.064 megapascals (3,200.1 psi; 217.75 atm; 220.64 bar). [3]
In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water. The glass of the jar is a different material, in its own separate phase. (See state of matter § Glass.)
At near-IR wavelengths, the characteristics of the 1.65, 3.1, and 4.53 μm water absorption lines are dependent on the ice temperature and crystal order. [160] The peak strength of the 1.65 μm band as well as the structure of the 3.1 μm band are particularly useful in identifying the crystallinity of water ice. [161] [162]
Triple points mark conditions at which three different phases can coexist. For example, the water phase diagram has a triple point corresponding to the single temperature and pressure at which solid, liquid, and gaseous water can coexist in a stable equilibrium (273.16 K and a partial vapor pressure of 611.657 Pa).
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