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The time-independent Schrödinger equation for the wave function is ^ = [+ ()] = (), where Ĥ is the Hamiltonian, ħ is the reduced Planck constant, m is the mass, E the energy of the particle. The step potential is simply the product of V 0 , the height of the barrier, and the Heaviside step function : V ( x ) = { 0 , x < 0 V 0 , x ≥ 0 ...
This generalizes to any number of particles in any number of dimensions (in a time-independent potential): the standing wave solutions of the time-independent equation are the states with definite energy, instead of a probability distribution of different energies.
which is an eigenvalue equation. Very often, only numerical solutions to the Schrödinger equation can be found for a given physical system and its associated potential energy. However, there exists a subset of physical systems for which the form of the eigenfunctions and their associated energies, or eigenvalues, can be found.
Thus the solutions () are just the Legendre functions ( ()) with =, and =,,, =,,,,. Moreover, eigenvalues and scattering data can be explicitly computed. [ 3 ] In the special case of integer λ {\displaystyle \lambda } , the potential is reflectionless and such potentials also arise as the N-soliton solutions of the Korteweg–De Vries ...
A stationary state is a quantum state with all observables independent of time. It is an eigenvector of the energy operator (instead of a quantum superposition of different energies). It is also called energy eigenvector, energy eigenstate, energy eigenfunction, or energy eigenket.
The time-independent Schrödinger equation for the wave function () reads ^ = [+ ()] = where ^ is the Hamiltonian, is the (reduced) Planck constant, is the mass, the energy of the particle and = [() ()] is the barrier potential with height > and width .
The entire vector ξ is a solution of the Schrödinger equation (with a suitable Hamiltonian), which unfolds to a coupled system of 2s + 1 ordinary differential equations with solutions ξ(s, t), ξ(s − 1, t), ..., ξ(−s, t). The term "spin function" instead of "wave function" is used by some authors.
The main effort in this approximate solution of the nuclear motion Schrödinger equation is the computation of the Hessian F of V and its diagonalization. This approximation to the nuclear motion problem, described in 3 N mass-weighted Cartesian coordinates, became standard in quantum chemistry , since the days (1980s-1990s) that algorithms for ...