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This generalizes to any number of particles in any number of dimensions (in a time-independent potential): the standing wave solutions of the time-independent equation are the states with definite energy, instead of a probability distribution of different energies.
The Inverse square root potential [2] The periodic potential The particle in a lattice; The particle in a lattice of finite length [3] The Pöschl–Teller potential; The quantum pendulum; The three-dimensional potentials The rotating system The linear rigid rotor; The symmetric top; The particle in a spherically symmetric potential
Thus the solutions () are just the Legendre functions ( ()) with =, and =,,, =,,,,. Moreover, eigenvalues and scattering data can be explicitly computed. [ 3 ] In the special case of integer λ {\displaystyle \lambda } , the potential is reflectionless and such potentials also arise as the N-soliton solutions of the Korteweg–De Vries ...
One particular solution to the time-independent Schrödinger equation is = /, a plane wave, which can be used in the description of a particle with momentum exactly p, since it is an eigenfunction of the momentum operator. These functions are not normalizable to unity (they are not square-integrable), so they are not really elements of physical ...
The time-independent Schrödinger equation for the wave function is ^ = [+ ()] = (), where Ĥ is the Hamiltonian, ħ is the reduced Planck constant, m is the mass, E the energy of the particle. The step potential is simply the product of V 0 , the height of the barrier, and the Heaviside step function : V ( x ) = { 0 , x < 0 V 0 , x ≥ 0 ...
One particle: N particles: One dimension ^ = ^ + = + ^ = = ^ + (,,) = = + (,,) where the position of particle n is x n. = + = = +. (,) = /.There is a further restriction — the solution must not grow at infinity, so that it has either a finite L 2-norm (if it is a bound state) or a slowly diverging norm (if it is part of a continuum): [1] ‖ ‖ = | |.
The main effort in this approximate solution of the nuclear motion Schrödinger equation is the computation of the Hessian F of V and its diagonalization. This approximation to the nuclear motion problem, described in 3 N mass-weighted Cartesian coordinates, became standard in quantum chemistry , since the days (1980s-1990s) that algorithms for ...
In the general time-independent case, the dynamics of a particle in a spherically symmetric potential are governed by a Hamiltonian of the following form: ^ = ^ + Here, is the mass of the particle, ^ is the momentum operator, and the potential () depends only on the vector magnitude of the position vector, that is, the radial distance from the ...