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Nitric oxide (nitrogen oxide or nitrogen monoxide [1]) is a colorless gas with the formula NO. It is one of the principal oxides of nitrogen . Nitric oxide is a free radical : it has an unpaired electron , which is sometimes denoted by a dot in its chemical formula ( • N=O or • NO).
Due to relatively weak N–O bonding, all nitrogen oxides are unstable with respect to N 2 and O 2, which is the principle behind the catalytic converter, and prevents the oxygen and nitrogen in the atmosphere from combusting.
Nitrogen oxides are released during manufacturing of nitrogen fertilizers. Though nitrous oxide is emitted during its application, it is then reacted in atmosphere to form nitrogen oxides. This third source is attributed to the reaction of atmospheric nitrogen, N 2, with radicals such as C, CH, and CH 2 fragments derived from fuel, [26] rather ...
One other possible oxide that has not yet been synthesised is oxatetrazole (N 4 O), an aromatic ring. [15] Nitrous oxide (N 2 O), better known as laughing gas, is made by thermal decomposition of molten ammonium nitrate at 250 °C. This is a redox reaction and thus nitric oxide and nitrogen are also produced as byproducts.
In general, nitric oxide is a poor nitrosant, Traube-type reactions notwithstanding. But atmospheric oxygen can oxidize nitric oxide to nitrogen dioxide, which does nitrosate. Alternatively cupric ions catalyze disproportionation into NO + and NO −. [5]
Nitrogen trioxide or nitrate radical is an oxide of nitrogen with formula NO 3 , consisting of three oxygen atoms covalently bound to a nitrogen atom. This highly unstable blue compound has not been isolated in pure form, but can be generated and observed as a short-lived component of gas, liquid, or solid systems.
Nitrogen forms two series of oxohalides with nitrogen in oxidation states 3, NOX, X = F, Cl, Br and 5, NO 2 X, X = F, Cl. They are made by halogenation of nitrogen oxides. Note that NO 2 F is isoelectronic with the nitrate ion, NO − 3. Only oxohalides of phosphorus(V) are known. [9]
The nitrosonium ion is NO +, in which the nitrogen atom is bonded to an oxygen atom with a bond order of 3, and the overall diatomic species bears a positive charge. It can be viewed as nitric oxide with one electron removed.