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The propagation of radiation through a medium is affected by absorption, emission, and scattering processes. The equation of radiative transfer describes these interactions mathematically. Equations of radiative transfer have application in a wide variety of subjects including optics, astrophysics, atmospheric science, and remote sensing.
HITRAN is a compilation of molecular spectroscopic parameters that a variety of computer codes use to predict and simulate the transmission and emission of light in the atmosphere. The original version was created at the Air Force Cambridge Research Laboratories (1960's).
The matter-composition of the medium through which the light travels determines the nature of the absorption and emission spectrum. These bands correspond to the allowed energy levels in the atoms. Dark bands in the absorption spectrum are due to the atoms in an intervening medium between source and observer. The atoms absorb certain ...
The emission spectrum of iron. Emission is a process by which a substance releases energy in the form of electromagnetic radiation. Emission can occur at any frequency at which absorption can occur, and this allows the absorption lines to be determined from an emission spectrum.
The energy of an electron is determined by its orbit around the atom, The n = 0 orbit, commonly referred to as the ground state, has the lowest energy of all states in the system. In atomic physics and chemistry , an atomic electron transition (also called an atomic transition, quantum jump, or quantum leap) is an electron changing from one ...
Spontaneous emission is the process in which a quantum mechanical system (such as a molecule, an atom or a subatomic particle) transits from an excited energy state to a lower energy state (e.g., its ground state) and emits a quantized amount of energy in the form of a photon. Spontaneous emission is ultimately responsible for most of the light ...
As a result, both absorption and emission produce molecules in vibrationally excited states. The potential wells are shown favoring transitions with changes in ν. The Franck-Condon principle describes the intensities of vibronic transitions, or the absorption or emission of a photon. It states that when a molecule is undergoing an electronic ...
That flux can be reduced by absorption, scattering or reflection, resulting in energy transmission over a path of less than 100%. The concept of radiative transfer extends beyond simple laboratory phenomena to include thermal emission of radiation by the medium - which can result in more photons arriving at the end of a path than entering it.