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  2. Free-radical halogenation - Wikipedia

    en.wikipedia.org/wiki/Free-radical_halogenation

    Free-radical halogenation. In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl -substituted aromatics under application of UV light. The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene.

  3. Halogenation - Wikipedia

    en.wikipedia.org/wiki/Halogenation

    Halogenation. In chemistry, halogenation is a chemical reaction which introduces one or more halogens into a chemical compound. Halide -containing compounds are pervasive, making this type of transformation important, e.g. in the production of polymers, drugs. [1] This kind of conversion is in fact so common that a comprehensive overview is ...

  4. Hydrohalogenation - Wikipedia

    en.wikipedia.org/wiki/Hydrohalogenation

    Hydrohalogenation. A hydrohalogenation reaction is the electrophilic addition of hydrogen halides like hydrogen chloride or hydrogen bromide to alkenes to yield the corresponding haloalkanes. [1][2][3] If the two carbon atoms at the double bond are linked to a different number of hydrogen atoms, the halogen is found preferentially at the carbon ...

  5. Haloalkane - Wikipedia

    en.wikipedia.org/wiki/Haloalkane

    Alkanes react with halogens by free radical halogenation. In this reaction a hydrogen atom is removed from the alkane, then replaced by a halogen atom by reaction with a diatomic halogen molecule. Free radical halogenation typically produces a mixture of compounds mono- or multihalogenated at various positions.

  6. Dehalogenation - Wikipedia

    en.wikipedia.org/wiki/Dehalogenation

    Dehalogenation. In organic chemistry, dehalogenation is a set of chemical reactions that involve the cleavage of carbon - halogen bonds; as such, it is the inverse reaction of halogenation. Dehalogenations come in many varieties, including defluorination (removal of fluorine), dechlorination (removal of chlorine), debromination (removal of ...

  7. Halogen addition reaction - Wikipedia

    en.wikipedia.org/wiki/Halogen_addition_reaction

    A halogen addition reaction is a simple organic reaction where a halogen molecule is added to the carbon–carbon double bond of an alkene functional group. [1] The general chemical formula of the halogen addition reaction is: C=C + X 2 → X−C−C−X. (X represents the halogens bromine or chlorine, and in this case, a solvent could be CH 2 ...

  8. Alkane - Wikipedia

    en.wikipedia.org/wiki/Alkane

    Free radicals, molecules with unpaired electrons, play a large role in most reactions of alkanes. Free radical halogenation reactions occur with halogens, leading to the production of haloalkanes. The hydrogen atoms of the alkane are progressively replaced by halogen atoms.

  9. Free-radical addition - Wikipedia

    en.wikipedia.org/wiki/Free-radical_addition

    Appearance. In organic chemistry, free-radical addition is an addition reaction which involves free radicals. These reactions can happen due to the free radicals having an unpaired electron in their valence shell, making them highly reactive. [ 1 ] Radical additions are known for a variety of unsaturated substrates, both olefinic or aromatic ...