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acetyl chloride SOCl 2 acetic acid (i) Li[AlH 4], ether (ii) H 3 O + ethanol Two typical organic reactions of acetic acid Acetic acid undergoes the typical chemical reactions of a carboxylic acid. Upon treatment with a standard base, it converts to metal acetate and water. With strong bases (e.g., organolithium reagents), it can be doubly deprotonated to give LiCH 2 COOLi. Reduction of acetic ...
This page provides supplementary chemical data on acetic acid. ... Structure and properties ... Vapor-liquid Equilibrium for Acetic acid/Water [3] P = 760 mm Hg BP Temp.
An acetate is a salt formed by the combination of acetic acid with a base (e.g. alkaline, earthy, metallic, nonmetallic or radical base). "Acetate" also describes the conjugate base or ion (specifically, the negatively charged ion called an anion) typically found in aqueous solution and written with the chemical formula C 2 H 3 O − 2.
It is sometimes produced in a laboratory experiment by the reaction of acetic acid, commonly in the 5–18% solution known as vinegar, with sodium carbonate ("washing soda"), sodium bicarbonate ("baking soda"), or sodium hydroxide ("lye", or "caustic soda"). Any of these reactions produce sodium acetate and water.
Trichloroacetic acid (TCA; TCAA; also known as trichloroethanoic acid) is an analogue of acetic acid in which the three hydrogen atoms of the methyl group have all been replaced by chlorine atoms. Salts and esters of trichloroacetic acid are called trichloroacetates .
Acetyl chloride was first prepared in 1852 by French chemist Charles Gerhardt by treating potassium acetate with phosphoryl chloride. [4]Acetyl chloride is produced in the laboratory by the reaction of acetic acid with chlorodehydrating agents such as phosphorus trichloride (PCl 3), phosphorus pentachloride (PCl 5), sulfuryl chloride (SO 2 Cl 2), phosgene, or thionyl chloride (SOCl 2).
It can be viewed as the result of homoassociation, an effect that enhances the acidity of acetic acid in concentrated solution: 2 CH 3 CO 2 H + NaOH → Na + [(CH 3 CO 2) 2 H] − + H 2 O. Also described as the sodium acid salt of acetic acid, it is best described as the sodium salt of the hydrogen-bonded anion (CH 3 CO 2) 2 H −.
The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst. [6] 2 C 2 H 4 + 2 CH 3 CO 2 H + O 2 → 2 CH 3 CO 2 CHCH 2 + 2 H 2 O. This method has replaced the addition of acetic acid to acetylene. The main side reaction is the combustion of organic precursors.