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The first constitutive equation (constitutive law) was developed by Robert Hooke and is known as Hooke's law.It deals with the case of linear elastic materials.Following this discovery, this type of equation, often called a "stress-strain relation" in this example, but also called a "constitutive assumption" or an "equation of state" was commonly used.
For completion, one must make hypotheses on the forms of τ and p, that is, one needs a constitutive law for the stress tensor which can be obtained for specific fluid families and on the pressure. Some of these hypotheses lead to the Euler equations (fluid dynamics) , other ones lead to the Navier–Stokes equations.
A surface mass on a surface given by the equation f (x, y, z) = 0 may be represented by a density distribution g(x, y, z) δ(f (x, y, z)), where / | | is the mass per unit area. The mathematical modelling can be done by potential theory , by numerical methods (e.g. a great number of mass points ), or by theoretical equilibrium figures.
The concept of a continuum underlies the mathematical framework for studying large-scale forces and deformations in materials. Although materials are composed of discrete atoms and molecules, separated by empty space or microscopic cracks and crystallographic defects, physical phenomena can often be modeled by considering a substance distributed throughout some region of space.
The law can be formulated mathematically in the fields of fluid mechanics and continuum mechanics, where the conservation of mass is usually expressed using the continuity equation, given in differential form as + =, where is the density (mass per unit volume), is the time, is the divergence, and is the flow velocity field.
The concept is the same as for a large mass balance, but it is performed in the context of a limiting system (for example, one can consider the limiting case in time or, more commonly, volume). A differential mass balance is used to generate differential equations that can provide an effective tool for modelling and understanding the target system.
This explains the duality in Darcy's law as a governing equation and a defining equation for absolute permeability. The non-linearity of the material derivative in balance equations in general, and the complexities of Cauchy's momentum equation and Navier-Stokes equation makes the basic equations in classical mechanics exposed to establishing ...
Mass transfer in a system is governed by Fick's first law: 'Diffusion flux from higher concentration to lower concentration is proportional to the gradient of the concentration of the substance and the diffusivity of the substance in the medium.' Mass transfer can take place due to different driving forces. Some of them are: [12]