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Methanation is the conversion of carbon monoxide and carbon dioxide (CO x) to methane (CH 4) through hydrogenation. The methanation reactions of CO x were first discovered by Sabatier and Senderens in 1902. [1] CO x methanation has many practical applications.
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Such diagrams are available in the speciality literature. [1] [2] [3] The same information can be depicted in a normal orthogonal diagram, showing only two substances, implicitly using the feature that the sum of all three components is 100 percent. The diagrams below only concerns one fuel; the diagrams can be generalized to mixtures of fuels.
CH 4 + H 2 O → CO + 3 H 2 Δ r H = +206 kJ mol −1 Water shift reaction CO + H 2 O → CO 2 + H 2 Δ r H = -41 kJ mol −1 Synthesis 2 H 2 + CO → CH 3 OH Δ r H = -92 kJ mol −1. The methanol thus formed may be converted to gasoline by the Mobil process and methanol-to-olefins.
C + H 2 O → CO + H 2 [1] CO + H 2 O → CO 2 + H 2 [1] C + CO 2 → 2CO [1] Steam reforming of methane is an endothermic reaction requiring 206 kJ/mol of methane: CH 4 + H 2 O → CO + 3 H 2. In principle, but rarely in practice, biomass and related hydrocarbon feedstocks could be used to generate biogas and biochar in waste-to-energy ...
Own work based on: File:Flammability diagram methane.png Redrawing of original by Power.corrupts as vector graphic. Possible source: Mashuga, CV; Crowl DA (1998). "Application of the flammability diagram for evaluation of fire and explosion hazards of flammable vapors". Process Safety Progress. 17 (3): 176–183. Author
Methane (CH 4) is one of the more potent greenhouse gases and is mainly produced by the digestion or decay of biological organisms. It is considered the second most important greenhouse gas, [10] yet the methane cycle in the atmosphere is currently only poorly understood. [11] The amount of methane produced and absorbed yearly varies widely. [10]
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