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Methanol is made from methane (natural gas) in a series of three reactions: Steam reforming CH 4 + H 2 O → CO + 3 H 2 Δ r H = +206 kJ mol −1 Water shift reaction CO + H 2 O → CO 2 + H 2 Δ r H = -41 kJ mol −1 Synthesis 2 H 2 + CO → CH 3 OH Δ r H = -92 kJ mol −1. The methanol thus formed may be converted to gasoline by the Mobil ...
Additional hydrogen is obtained by the reaction of CO with water via the water-gas shift reaction: CO + H 2 O ⇌ CO 2 + H 2. This reaction is mildly exothermic (produces heat, ΔH r = −41 kJ/mol). Methane is also subjected to free-radical chlorination in the production of chloromethanes, although methanol is a more typical precursor. [35]
With a compressed natural gas (CNG) engine, the mixing of the fuel and the air is more effective since gases typically mix well in a short period of time, but at typical CNG pressures the fuel itself is less energy-dense than gasoline or diesel, so the result is a less energy-dense air–fuel mixture. For an engine of a given cylinder ...
The water–gas shift reaction (WGSR) describes the reaction of carbon monoxide and water vapor to form carbon dioxide and hydrogen: CO + H 2 O ⇌ CO 2 + H 2. The water gas shift reaction was discovered by Italian physicist Felice Fontana in 1780. It was not until much later that the industrial value of this reaction was realized.
Using liquid methane and liquid oxygen as propellants is sometimes called methalox propulsion. [19] Liquid methane has a lower specific impulse than liquid hydrogen, but is easier to store due to its higher boiling point and density, as well as its lack of hydrogen embrittlement. It also leaves less residue in the engines compared to kerosene ...
Paul Sabatier (1854-1941) winner of the Nobel Prize in Chemistry in 1912 and discoverer of the reaction in 1897. The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa [1]) in the presence of a nickel catalyst.
It also contains lesser amount of other gases. [10] Syngas has less than half the energy density of natural gas. [11] The first reaction, between incandescent coke and steam, is strongly endothermic, producing carbon monoxide (CO) and hydrogen H 2 (water gas in older terminology). When the coke bed has cooled to a temperature at which the ...
Methanol is a promising energy carrier because, as a liquid, it is easier to store than hydrogen and natural gas. Its energy density is, however, lower than methane, per kg. Its combustion energy density is 15.6 MJ/L , whereas that of ethanol is 24 and gasoline is 33 MJ/L.