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In kinetic theory of gases, the mean free path is the average distance traveled by a molecule, or a number of molecules per volume, before they make their first collision. Let σ {\displaystyle \sigma } be the collision cross section of one molecule colliding with another.
As the construct that gases are small particles in Brownian motion became widely accepted and numerous quantitative studies verifying that the macroscopic properties of gases, such as temperature, pressure and density, are the results of collisions of moving particles, [3] the study of kinetic theory of gases became increasingly an integrated ...
The kinetic theory of gases applies to the classical ideal gas, which is an idealization of real gases. In real gases, there are various effects (e.g., van der Waals interactions , vortical flow, relativistic speed limits, and quantum exchange interactions ) that can make their speed distribution different from the Maxwell–Boltzmann form.
Kinetic theory may refer to: Kinetic theory of matter: A general account of the properties of matter, including solids liquids and gases, based around the idea that heat or temperature is a manifestation of atoms and molecules in constant agitation. Kinetic theory of gases, an account of gas properties in terms of motion and interaction of ...
The kinetic theory of gases allows accurate calculation of the temperature-variation of gaseous viscosity. The theoretical basis of the kinetic theory is given by the Boltzmann equation and Chapman–Enskog theory, which allow accurate statistical modeling of molecular trajectories.
Kinetic theory of gases [ edit ] In the kinetic theory of gases , the mean free path of a particle, such as a molecule , is the average distance the particle travels between collisions with other moving particles.
John James Waterston (1811 – 18 June 1883) was a Scottish physicist and a neglected pioneer of the kinetic theory of gases. Early life. Waterston's father, ...
By modeling matter as collections of hard spheres, it is possible to describe the kinetic theory of gases, upon which classical thermodynamics is based. Thermodynamics studies the effects of changes in temperature, pressure, and volume on physical systems on the macroscopic scale, and the transfer of energy as heat.