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Naphthalene is a major component of some mothballs.It repels moths as well as some animals. [citation needed]Since mothballs that contain naphthalene are considered hazards, safer alternatives have been developed, such as the use of 1,4-dichlorobenzene, however, 1,4-dichlorobenzene has been declared as a potential neurotoxin. 1,4-dichlorobenzene has been linked to potentially causing ...
1-Naphthol, or α-naphthol, is an organic compound with the formula C 10 H 7 OH. It is a fluorescent white solid. 1-Naphthol differs from its isomer 2-naphthol by the location of the hydroxyl group on the naphthalene ring. The naphthols are naphthalene homologues of phenol. Both isomers are soluble in simple organic solvents. They are ...
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Carbaryl is often inexpensively produced by direct reaction of methyl isocyanate with 1-naphthol. [5]C 10 H 7 OH + CH 3 NCO → C 10 H 7 OC(O)NHCH 3. Alternatively, 1-naphthol can be treated with excess phosgene to produce 1-naphthyl chloroformate, which is then converted to carbaryl by reaction with methylamine. [5]
1,4-Naphthoquinone acts as strong dienophile in Diels-Alder reaction.Its adduct with 1,3-butadiene can be prepared by two methods: 1) long (45 days) exposure of naphthoquinone in neat liquid butadiene taken in huge excess at room temperature in a thick-wall glass tube or 2) fast catalyzed cycloaddition at low temperature in the presence of 1 equivalent of tin(IV) chloride: [5]
The bonds C1−C2, C3−C4, C5−C6 and C7−C8 are about 1.37 Å (137 pm) in length, whereas the other carbon–carbon bonds are about 1.42 Å (142 pm) long. This difference, established by X-ray diffraction , [ 21 ] is consistent with the valence bond model in naphthalene and in particular, with the theorem of cross-conjugation .
The absence of any hazard class or division or a blank space in the table indicates that no restrictions apply. X : These materials may not be loaded, transported, or stored together in the same transport vehicle or storage facility during the course of transportation.