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The clock system is easily converted into a 360 degree system for more precise denotation. One bearing, or point, is termed an azimuth. [2] The convention is that of analytic geometry: the y-axis at zero degrees is the longitudinal axis of the vehicle. Angles grow larger in the clockwise direction. Thus, directly to port is at 270 degrees.
In the new coordinate system, the point P will appear to have been rotated in the opposite direction, that is, clockwise through the angle . A rotation of axes in more than two dimensions is defined similarly. [2] [3] A rotation of axes is a linear map [4] [5] and a rigid transformation.
[4] [5] Every set of three non-colinear atoms of a molecule defines a half-plane. As explained above, when two such half-planes intersect (i.e., a set of four consecutively-bonded atoms), the angle between them is a dihedral angle. Dihedral angles are used to specify the molecular conformation. [6]
Clockwise motion (abbreviated CW) proceeds in the same direction as a clock's hands relative to the observer: from the top to the right, then down and then to the left, and back up to the top. The opposite sense of rotation or revolution is (in Commonwealth English ) anticlockwise ( ACW ) or (in North American English ) counterclockwise ( CCW ...
Recording optical rotation with a polarimeter: The plane of polarisation of plane polarised light (4) rotates (6) as it passes through an optically active sample (5). This angle is determined with a rotatable polarizing filter (7). In chemistry, specific rotation ([α]) is a property of a chiral chemical compound.
are arranged around the chiral center carbon atom. With the hydrogen atom away from the viewer, if the arrangement of the CO→R→N groups around the carbon atom as center is counter-clockwise, then it is the L form. [14] If the arrangement is clockwise, it is the D form. As usual, if the molecule itself is oriented differently, for example ...
Other disciplines use different terms (such as dextro-and laevo-rotary in chemistry, or clockwise and anticlockwise in physics) or simply use left and right (as in anatomy). Relative direction and chirality are distinct concepts.
Lowest priority (i.e. number 4) is given to the hydrogen atom and as this atom points away from the viewer, the counterclockwise decrease in priority over the three remaining substituents completes the assignment as S. The stereocenter in -carvone is connected to one