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Carbon tetrachloride, also known by many other names (such as carbon tet for short and tetrachloromethane, also recognised by the IUPAC), is a chemical compound with the chemical formula CCl 4. It is a non-flammable, dense, colourless liquid with a "sweet" chloroform-like odour that can be detected at low levels.
1,1,1,3,3,3-Hexachloropropane is a compound of chlorine, hydrogen, and carbon, with chemical formula C 3 Cl 6 H 2, specifically Cl 3 C−CH 2 −CCl 3. Its molecule can be described as that of propane with chlorine atoms substituted for the six hydrogen atoms on the extremal carbons.
The Appel reaction is an organic reaction that converts an alcohol into an alkyl chloride using triphenylphosphine and carbon tetrachloride. [1] The use of carbon tetrabromide or bromine as a halide source will yield alkyl bromides, whereas using carbon tetraiodide, methyl iodide or iodine gives alkyl iodides. The reaction is credited to and ...
Apart from the decomposition of N 2 O 5 at high temperatures, it can also be decomposed in carbon tetrachloride CCl 4 at 30 °C (303 K). [20] Both N 2 O 5 and NO 2 are soluble in CCl 4 and remain in solution while oxygen is insoluble and escapes. The volume of the oxygen formed in the reaction can be measured in a gas burette.
Chloroform undergoes further chlorination to yield carbon tetrachloride (CCl 4): CHCl 3 + Cl 2 → CCl 4 + HCl The output of this process is a mixture of the four chloromethanes: chloromethane , methylene chloride (dichloromethane), trichloromethane (chloroform), and tetrachloromethane (carbon tetrachloride).
In addition, a variety of simple chlorinated hydrocarbons including dichloromethane, chloroform, and carbon tetrachloride have been isolated from marine algae. [7] A majority of the chloromethane in the environment is produced naturally by biological decomposition, forest fires, and volcanoes.
Structure and properties Index of refraction, n D: 1.460 Abbe number? Dielectric constant, ε r: 2.2379 ε 0 at 20 °C : Bond strength? Bond length: 175pm Bond angle: 109.5° Cl–C–Cl
Trichlorofluoromethane can be obtained by reacting carbon tetrachloride with hydrogen fluoride at 435 °C and 70 atm, producing a mixture of trichlorofluoromethane, tetrafluoromethane and dichlorodifluoromethane in a ratio of 77:18:5. The reaction can also be carried out in the presence of antimony(III) chloride or antimony(V) chloride: [8]