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Three-dimensional representations of several fatty acids. Saturated fatty acids have perfectly straight chain structure. Unsaturated ones are typically bent, unless they have a trans configuration. In chemistry, particularly in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated or unsaturated.
All polymers are made of repetitive units called monomers. Biopolymers often have a well-defined structure, though this is not a defining characteristic (example: lignocellulose): The exact chemical composition and the sequence in which these units are arranged is called the primary structure, in the case of proteins.
[2]: 634 Fatty acids are made by fatty acid synthases that polymerize and then reduce acetyl-CoA units. The acyl chains in the fatty acids are extended by a cycle of reactions that add the acetyl group, reduce it to an alcohol, dehydrate it to an alkene group and then reduce it again to an alkane group.
Alkyds are derived from polyols and organic acids including dicarboxylic acids or carboxylic acid anhydride and triglyceride oils. The term alkyd is a modification of the original name "alcid", reflecting the fact that they are derived from alcohol and organic acids. [2] The inclusion of a fatty acid confers a tendency to form flexible coatings.
Most lipids consist of a polar or hydrophilic head (typically glycerol) and one to three non polar or hydrophobic fatty acid tails, and therefore they are amphiphilic. Fatty acids consist of unbranched chains of carbon atoms that are connected by single bonds alone (saturated fatty acids) or by both single and double bonds (unsaturated fatty ...
Tetradecanoic acid CH 3 (CH 2) 12 COOH C14:0 Pentadecylic acid: Pentadecanoic acid CH 3 (CH 2) 13 COOH C15:0 Palmitic acid: Hexadecanoic acid CH 3 (CH 2) 14 COOH C16:0 Margaric acid: Heptadecanoic acid CH 3 (CH 2) 15 COOH C17:0 Stearic acid: Octadecanoic acid CH 3 (CH 2) 16 COOH C18:0 Nonadecylic acid: Nonadecanoic acid CH 3 (CH 2) 17 COOH C19 ...
Fatty acids, monoglycerides (one glycerol, one fatty acid), and some diglycerides are absorbed by the duodenum, once the triglycerides have been broken down. In the intestine , following the secretion of lipases and bile , triglycerides are split into monoacylglycerol and free fatty acids in a process called lipolysis .
Synthesis of saturated fatty acids via fatty acid synthase II in E. coli. Straight-chain fatty acid synthesis occurs via the six recurring reactions shown below, until the 16-carbon palmitic acid is produced. [2] [3] The diagrams presented show how fatty acids are synthesized in microorganisms and list the enzymes found in Escherichia coli. [2]