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The term calcium phosphate refers to a family of materials and minerals containing calcium ions (Ca 2+) together with inorganic phosphate anions. Some so-called calcium phosphates contain oxide and hydroxide as well. Calcium phosphates are white solids of nutritional value [2] and are found in many living organisms, e.g., bone mineral and tooth ...
Tricalcium phosphate (sometimes abbreviated TCP), more commonly known as Calcium phosphate, is a calcium salt of phosphoric acid with the chemical formula Ca 3 (PO 4) 2. It is also known as tribasic calcium phosphate and bone phosphate of lime (BPL). It is a white solid of low solubility.
Dicalcium phosphate is the calcium phosphate with the formula CaHPO 4 and its dihydrate. The "di" prefix in the common name arises because the formation of the HPO 4 2– anion involves the removal of two protons from phosphoric acid, H 3 PO 4. It is also known as dibasic calcium phosphate or calcium monohydrogen phosphate.
Monocalcium phosphate is an inorganic compound with the chemical formula Ca(H 2 PO 4) 2 ("AMCP" or "CMP-A" for anhydrous monocalcium phosphate). It is commonly found as the monohydrate ("MCP" or "MCP-M"), Ca(H 2 PO 4) 2 ·H 2 O. Both salts are colourless solids.
This means that salts of the mono- and di-phosphate ions can be selectively crystallised from aqueous solution by setting the pH value to either 4.7 or 9.8. In effect, H 3 PO 4, H 2 (PO 4) − and H(PO 4) 2− behave as separate weak acids because the successive pK a differ by more than 4. Phosphate can form many polymeric ions such as ...
Octacalcium phosphate (sometimes referred to as OCP) is a form of calcium phosphate with formula Ca 8 H 2 (PO 4) 6 ·5H 2 O. [1] OCP may be a precursor to tooth enamel , dentine , and bones . OCP is a precursor of hydroxyapatite (HA), an inorganic biomineral that is important in bone growth. [ 2 ]
The dihydrate, sometimes termed CPPD, can be formed by the reaction of pyrophosphoric acid with calcium chloride: [citation needed] CaCl 2 + H 4 P 2 O 7 (aq) → Ca 2 P 2 O 7 ·2 H 2 O + HCl. The anhydrous forms can be prepared by heating dicalcium phosphate: [2] 2 CaHPO 4 → Ca 2 P 2 O 7 + H 2 O
Tetracalcium phosphate is the compound Ca 4 (PO 4) 2 O, (4CaO·P 2 O 5). It is the most basic of the calcium phosphates, and has a Ca/P ratio of 2, making it the most phosphorus poor phosphate. [1] It is found as the mineral hilgenstockite, which is formed in industrial phosphate rich