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  2. Limiting reagent - Wikipedia

    en.wikipedia.org/wiki/Limiting_reagent

    One reactant (A) is chosen, and the balanced chemical equation is used to determine the amount of the other reactant (B) necessary to react with A. If the amount of B actually present exceeds the amount required, then B is in excess and A is the limiting reagent. If the amount of B present is less than required, then B is the limiting reagent.

  3. Reaction progress kinetic analysis - Wikipedia

    en.wikipedia.org/wiki/Reaction_progress_kinetic...

    Here, a same-excess (e = 0.60 M) of [ArX] relative to [HNR 2] and [MOR] is utilized for each of the curves. As described above, same-excess experiments are conducted with two or more experiments holding the excess, (e) constant while changing the absolute concentrations of the substrates (in this case, the catalyst is also treated as a substrate.)

  4. Stoichiometry - Wikipedia

    en.wikipedia.org/wiki/Stoichiometry

    The limiting reagent is the reagent that limits the amount of product that can be formed and is completely consumed when the reaction is complete. An excess reactant is a reactant that is left over once the reaction has stopped due to the limiting reactant being exhausted.

  5. Excess property - Wikipedia

    en.wikipedia.org/wiki/Excess_property

    In chemical thermodynamics, excess properties are properties of mixtures which quantify the non-ideal behavior of real mixtures. They are defined as the difference between the value of the property in a real mixture and the value that would exist in an ideal solution under the same conditions.

  6. Carothers equation - Wikipedia

    en.wikipedia.org/wiki/Carothers_equation

    r is the stoichiometric ratio of reactants, the excess reactant is conventionally the denominator so that r < 1. If neither monomer is in excess, then r = 1 and the equation reduces to the equimolar case above. The effect of the excess reactant is to reduce the degree of polymerization for a given value of p.

  7. Conversion (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Conversion_(chemistry)

    Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...

  8. Yield (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Yield_(chemistry)

    Stoichiometric equations are used to determine the limiting reagent or reactant—the reactant that is completely consumed in a reaction. The limiting reagent determines the theoretical yield—the relative quantity of moles of reactants and the product formed in a chemical reaction. Other reactants are said to be present in excess.

  9. Reaction rate constant - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate_constant

    where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here ⁠ ⁠ is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...

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