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Lithium chloride is a chemical compound with the formula Li Cl.The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li + ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.
Solid properties Std enthalpy of formation Δ f H o solid: −408.27 kJ/mol Standard molar entropy S o solid: 59.33 J/(mol K) Heat capacity c p: 47.99 J/(mol K) Liquid properties Std enthalpy of formation Δ f H o liquid: −390.76 kJ/mol Standard molar entropy S o liquid? J/(mol K) Heat capacity c p? J/(mol K) Gas properties Std enthalpy of ...
Cyanide and chloride salt mixtures are used for surface modification of alloys such as carburizing and nitrocarburizing of steel. Cryolite (a fluoride salt) is used as a solvent for aluminium oxide in the production of aluminium in the Hall-Héroult process. Fluoride, chloride, and hydroxide salts can be used as solvents in pyroprocessing of ...
Lithium bromide was used as a sedative beginning in the early 1900s, but it fell into disfavor in the 1940s as newer sedatives became available and when some heart patients died after using the salt substitute lithium chloride. [11] Like lithium carbonate and lithium chloride, it was used as treatment for bipolar disorder.
Both lithium-6 and lithium-7 produce tritium when irradiated by neutrons, and are thus useful for the production of tritium by itself, as well as a form of solid fusion fuel used inside hydrogen bombs in the form of lithium deuteride. The US became the prime producer of lithium between the late 1950s and the mid-1980s.
Lithium tetrachloroaluminate is used in some lithium batteries. A solution of lithium tetrachloroaluminate in thionyl chloride is the liquid cathode and electrolyte in those baterries, e.g. the lithium-thionyl chloride cell. Another cathode-electrolyte formulation is lithium tetrachloroaluminate + thionyl chloride + sulfur dioxide + bromine.
Lithium perchlorate is also used as an electrolyte salt in lithium-ion batteries.Lithium perchlorate is chosen over alternative salts such as lithium hexafluorophosphate or lithium tetrafluoroborate when its superior electrical impedance, conductivity, hygroscopicity, and anodic stability properties are of importance to the specific application. [11]
Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid that transitions to white with decreasing crystal size. Its structure is analogous to that of sodium chloride, but it is much less soluble in water.
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