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Anthocyanins belong to a parent class of molecules called flavonoids synthesized via the phenylpropanoid pathway. They can occur in all tissues of higher plants, including leaves, stems, roots, flowers, and fruits. Anthocyanins are derived from anthocyanidins by adding sugars. [3] They are odorless and moderately astringent.
Ideain is the main anthocyanin in red-skinned [1] or red-fleshed (for example Weirouge) [2] apple varieties. It is also found in Chinese hawthorn fruits (Crataegus spp.). [3]It is also the pigment in the copper beech (cultivar of Fagus sylvatica), that was identified in 1932.
In bryophytes, anthocyanins are usually based on 3-desoxyanthocyanidins located in the cell wall. A new anthocyanidin, riccionidin A, has been isolated from the liverwort Ricciocarpos natans . It could be derived from 6,7,2′,4′,6′-pentahydroxyflavylium, having undergone ring closure of the 6’ -hydroxyl at the 3-position.
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These complexes are self-assembled, supramolecular metal complex pigment composed of stoichiometric amounts of anthocyanins, flavones, and metal ions. The various colors, such as red, mauve, purple, violet and blue, in Hydrangea macrophylla are developed from one simple anthocyanin, delphinidin 3-glucoside forming complexes with metal ions.
Leucoanthocyanidin (flavan-3,4-diols) are colorless chemical compounds related to anthocyanidins and anthocyanins.Leucoanthocyanins can be found in Anadenanthera peregrina and in several species of Nepenthes including N. burbidgeae, N. muluensis, N. rajah, N. tentaculata, and N. × alisaputrana.
Condensed tannins may be characterised by a number of techniques including depolymerisation, asymmetric flow field flow fractionation or small-angle X-ray scattering.. DMACA is a dye that is particularly useful for localization of proanthocyanidin compounds in plant histology.
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