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In physics and physical chemistry, time-resolved spectroscopy is the study of dynamic processes in materials or chemical compounds by means of spectroscopic techniques.Most often, processes are studied after the illumination of a material occurs, but in principle, the technique can be applied to any process that leads to a change in properties of a material.
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly ...
Pulsed electron paramagnetic resonance (EPR) is an electron paramagnetic resonance technique that involves the alignment of the net magnetization vector of the electron spins in a constant magnetic field. This alignment is perturbed by applying a short oscillating field, usually a microwave pulse.
Electron paramagnetic resonance (EPR) spectroscopy is dedicated to researching substances with unpaired electrons. It was first introduced in 1944, approximately the same time as a similar phenomenon - nuclear magnetic resonance (NMR). [10] [11] Owing to hardware and software limitations, EPR was not developing as rapidly as NMR. This led to a ...
Electron nuclear double resonance (ENDOR) is a magnetic resonance technique for elucidating the molecular and electronic structure of paramagnetic species. [1] The technique was first introduced to resolve interactions in electron paramagnetic resonance (EPR) spectra.
Spin trapping is an analytical technique employed in chemistry [1] and biology [2] for the detection and identification of short-lived free radicals through the use of electron paramagnetic resonance (EPR) spectroscopy. EPR spectroscopy detects paramagnetic species such as the unpaired electrons of free
The interaction of an electromagnetic wave with an electron bound in an atom or molecule can be described by time-dependent perturbation theory. Magnetic dipole transitions describe the dominant effect of the coupling of the magnetic dipole moment of the electron to the magnetic part of the electromagnetic wave. They can be divided into two ...
Electric dipole spin resonance (EDSR) is the coupling of the electron spin with an oscillating electric field. Similar to the electron spin resonance (ESR) in which electrons can be excited with an electromagnetic wave with the energy given by the Zeeman effect , in EDSR the resonance can be achieved if the frequency is related to the energy ...