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1) to help visualize ionically related waters from which a flow path can be determined, or; 2) if the flow path is known, to show how the ionic composition of a water body changes over space and/or time. Example of a Stiff diagram. A typical Stiff diagram is shown in the figure (right).
An aqueous solution containing 120 mg NaHCO 3 (baking soda) per litre of water will contain 1.4285 mmol/l of bicarbonate, since the molar mass of baking soda is 84.007 g/mol. This is equivalent in carbonate hardness to a solution containing 0.71423 mmol/L of (calcium) carbonate, or 71.485 mg/L of calcium carbonate (molar mass 100.09 g/mol).
Normality is defined as the number of gram or mole equivalents of solute present in one liter of solution.The SI unit of normality is equivalents per liter (Eq/L). = where N is normality, m sol is the mass of solute in grams, EW sol is the equivalent weight of solute, and V soln is the volume of the entire solution in liters.
Alkalinity is typically reported as mg/L as CaCO 3. (The conjunction "as" is appropriate in this case because the alkalinity results from a mixture of ions but is reported "as if" all of this is due to CaCO 3.) This can be converted into milliequivalents per Liter (meq/L) by dividing by 50 (the approximate MW of CaCO 3 divided by 2).
The solution has 1 mole or 1 equiv Na +, 1 mole or 2 equiv Ca 2+, and 3 mole or 3 equiv Cl −. An earlier definition, used especially for chemical elements , holds that an equivalent is the amount of a substance that will react with 1 g (0.035 oz) of hydrogen , 8 g (0.28 oz) of oxygen , or 35.5 g (1.25 oz) of chlorine —or that will displace ...
RSC is expressed in meq/L units. RSC should not be higher than 1 and preferably less than +0.5 for considering the water use for irrigation. [5] The formula for calculating RSC index is: RSC index = [HCO 3 + CO 3] − [Ca + Mg] RSC index = HCO 3 /61 + CO 3 /30 – Ca/20 – Mg/12 (in case the ionic concentrations are measured in mg/L or ppm as ...
In chemistry, the mass concentration ρ i (or γ i) is defined as the mass of a constituent m i divided by the volume of the mixture V. [1]= For a pure chemical the mass concentration equals its density (mass divided by volume); thus the mass concentration of a component in a mixture can be called the density of a component in a mixture.
[1] Piper diagram of water samples from the Mtshabezi River, Zimbabwe. Data source: [2] A Piper diagram is a graphical representation of the chemistry of a water sample or samples. The cations and anions are shown by separate ternary plots. The apexes of the cation plot are calcium, magnesium and sodium plus potassium cations.