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2,6-Di-tert-butylphenol is an organic compound with the structural formula 2,6-((CH 3) 3 C) 2 C 6 H 3 OH.This colorless solid alkylated phenol and its derivatives are used industrially as UV stabilizers and antioxidants for hydrocarbon-based products ranging from petrochemicals to plastics. [1]
The chemical synthesis of BHT in industry has involved the reaction of p-cresol (4-methylphenol) with isobutylene (2-methylpropene), catalyzed by sulfuric acid: [11] CH 3 (C 6 H 4)OH + 2 CH 2 =C(CH 3) 2 → ((CH 3) 3 C) 2 CH 3 C 6 H 2 OH. Alternatively, BHT has been prepared from 2,6-di-tert-butylphenol by hydroxymethylation or aminomethylation ...
2-tert-Butylphenol is an intermediate in the industrial production of 2,6-di-tert-butylphenol, a common antioxidant. [2] Hydrogenation of 2-tert-butylphenol gives cis-2-tert-butylcyclohexanol, which when acetylated is a commercial fragrance. [2]
2,4-Di-tert-butylphenol (2,4-DTBP) is a white solid with a phenolic odour. It is primarily used as a raw material for the production of several commercially important antioxidants and phenolic benzotriazole -type UV absorbers .
This alkylation provides a means to separate 2,4-xylenol from 2,5-xylenol since 2,4-dimethyl-6-tert-butylphenol is insoluble in 10% NaOH but 2,5-dimethyl-6-tert-butylphenol is soluble. Subsequent to separation, the tert-butyl group can be removed in strong acid. [1]
UV-328 (2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenol) is a chemical compound that belongs to the phenolic benzotriazoles. It is a UV filter that is used as an antioxidant for plastics. It is a UV filter that is used as an antioxidant for plastics.
[2] [3] As the direct oxidative coupling of phenol gives a mixture of isomers, [4] [5] 4,4′-biphenol is instead prepared from 2,6-di-tert-butylphenol, where para-coupling is the only possibility. [3] A reaction with oxygen produces phenol-radicals which undergo rapid dimerisation, ultimately forming a diphenoquinone.
[5] 2,4,6-tri-tert-butylphenol is also found as a by-product in the synthesis of the disubstitution products 2,4-DTBP and 2,6-DTBP, which are more widely used antioxidants. [2] Synthese von 2,4,6-Tri-tert-butylphenol mit Isobuten. A synthesis of 2,4,6-tri-tert-butylphenol has been described that is also suitable as a teaching experiment.