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Electronegativity, symbolized as χ, is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond. [1] An atom's electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the ...
The tendency of an atom in a molecule to attract the shared pair of electrons towards itself is known as electronegativity. It is a dimensionless quantity because it is only a tendency. [16] The most commonly used scale to measure electronegativity was designed by Linus Pauling. The scale has been named the Pauling scale in his honour.
Electronegativity is not a uniquely defined property and may depend on the definition. The suggested values are all taken from WebElements as a consistent set. Many of the highly radioactive elements have values that must be predictions or extrapolations, but are unfortunately not marked as such.
This applies for both electrolytic and electrochemical cells, though the charge on them reverses. The red cat and an ox mnemonics are useful to remember the same. Red cat: Reduction at cathode; An ox: Anode for oxidation. [32] PANIC : Positive Anode, Negative Is Cathode; The words oxidation and anode, both begin with vowels.
A list of the electron affinities was used by Robert S. Mulliken to develop an electronegativity scale for atoms, equal to the average of the electrons affinity and ionization potential. [2] [3] Other theoretical concepts that use electron affinity include electronic chemical potential and chemical hardness.
Bent's rule can be extended to rationalize the hybridization of nonbonding orbitals as well. On the one hand, a lone pair (an occupied nonbonding orbital) can be thought of as the limiting case of an electropositive substituent, with electron density completely polarized towards the central atom.
In 1951, Sanderson developed the idea of electronegativity equalization, stating two bonding atoms will equalize their Mulliken electronegativity. [1] He would later further revise his own scale of electronegativity to adhere to the 4.00 value of fluorine found in the more common Pauling scale, as well as apply his principle to the calculation of polar covalent bonds, calculating partial ...
The Nature of the Chemical Bond. 3rd ed., Cornell University Press, p. 93. 93. ^ The electronegativity of francium was chosen by Pauling as 0.7, close to that of caesium (also assessed 0.7 at that point).