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American YouTube personality MrBeast is the most-subscribed channel on YouTube, with 346 million subscribers as of January 2025.. A subscriber to a channel on the American video-sharing platform YouTube is a user who has chosen to receive the channel's content by clicking on that channel's "Subscribe" button, and each user's subscription feed consists of videos published by channels to which ...
In 1962, Edwards and Pearson (the latter of HSAB theory) introduced the phrase alpha effect for this anomaly. He offered the suggestion that the effect was caused by a transition state (TS) stabilization effect: on entering the TS the free electron pair on the nucleophile moves away from the nucleus, causing a partial positive charge which can be stabilized by an adjacent lone pair as for ...
In general, in a group across the periodic table, the more basic the ion (the higher the pK a of the conjugate acid) the more reactive it is as a nucleophile. Within a series of nucleophiles with the same attacking element (e.g. oxygen), the order of nucleophilicity will follow basicity.
Organometallic compounds of electropositive metals are superbases, but they are generally strong nucleophiles. Examples include organolithium and organomagnesium ( Grignard reagent ) compounds. Another type of organometallic superbase has a reactive metal exchanged for a hydrogen on a heteroatom , such as oxygen (unstabilized alkoxides ) or ...
As the name suggests, a non-nucleophilic base is a sterically hindered organic base that is a poor nucleophile.Normal bases are also nucleophiles, but often chemists seek the proton-removing ability of a base without any other functions.
Alongside his wife Elizabeth, they maintain a YouTube channel taitled Big Loz Official [12] sponsored by Cerberus Strength. Since 2016, the channel has covered many strongman-related topics including training, event coverage, athletes and competition analysis, strongman history, trivia, predictions, new developments and live Q&A sessions with ...
Seed oils, including peanut oil and sunflower oil, have been in the news a lot recently. Dietitians explain if seed oils are healthy, and health risks of them.
Others, however, insist that such a usage is an abuse of terminology, and limit the Michael addition to the formation of carbon–carbon bonds through the addition of carbon nucleophiles. The terms oxa-Michael reaction and aza-Michael reaction [2] have been used to refer to the 1,4-addition of oxygen and nitrogen nucleophiles, respectively. The ...