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Naturally occurring vanadium is composed of one stable isotope, 51 V, and one radioactive isotope, 50 V. The latter has a half-life of 2.71×10 17 years and a natural abundance of 0.25%. 51 V has a nuclear spin of 7 ⁄ 2 , which is useful for NMR spectroscopy . [ 25 ]
Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements , niobium and tantalum , are somewhat more limited to the +5 oxidation state. [ 1 ]
The cross product with respect to a right-handed coordinate system. In mathematics, the cross product or vector product (occasionally directed area product, to emphasize its geometric significance) is a binary operation on two vectors in a three-dimensional oriented Euclidean vector space (named here ), and is denoted by the symbol .
These tables list values of molar ionization energies, measured in kJ⋅mol −1.This is the energy per mole necessary to remove electrons from gaseous atoms or atomic ions.
Vanadium forms oxides in the +2, +3, +4 and +5 oxidation states, forming vanadium(II) oxide (VO), vanadium(III) oxide (V 2 O 3), vanadium(IV) oxide (VO 2) and vanadium(V) oxide (V 2 O 5). Vanadium(V) oxide or vanadium pentoxide is the most common, being precursor to most alloys and compounds of vanadium, and is also a widely used industrial ...
Pissoort mentioned the possibility of VRFBs in the 1930s. [9] NASA researchers and Pellegri and Spaziante followed suit in the 1970s, [10] but neither was successful. Maria Skyllas-Kazacos presented the first successful demonstration of an All-Vanadium Redox Flow Battery employing dissolved vanadium in a solution of sulfuric acid in the 1980s.
Charge quantization is the principle that the charge of any object is an integer multiple of the elementary charge. Thus, an object's charge can be exactly 0 e, or exactly 1 e, −1 e, 2 e, etc., but not 1 / 2 e, or −3.8 e, etc. (There may be exceptions to this statement, depending on how "object" is defined; see below.)
C corresponds to the electronic charge of the species relative to the site that it occupies. The charge of the species is calculated by the charge on the current site minus the charge on the original site. To continue the previous example, Ni often has the same valency as Cu, so the relative charge is zero. To indicate a null charge, × is used