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The limiting reagent (or limiting reactant or limiting agent) in a chemical reaction is a reactant that is totally consumed when the chemical reaction is completed. [ 1 ] [ 2 ] The amount of product formed is limited by this reagent, since the reaction cannot continue without it.
To find the limiting reagent and the mass of HCl produced by the reaction, we change the above amounts by a factor of 90/324.41 and obtain the following amounts: 90.00 g FeCl 3, 28.37 g H 2 S, 57.67 g Fe 2 S 3, 60.69 g HCl. The limiting reactant (or reagent) is FeCl 3, since all 90.00 g of it is used up while only 28.37 g H 2 S are consumed.
The limiting reagent determines the theoretical yield—the relative quantity of moles of reactants and the product formed in a chemical reaction. Other reactants are said to be present in excess. The actual yield—the quantity physically obtained from a chemical reaction conducted in a laboratory—is often less than the theoretical yield. [8]
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
2,4,6-Trichlorobenzoyl chloride or Yamaguchi's reagent is an chlorinated aromatic compound that is commonly used in a variety of organic syntheses. [ 2 ] [ 3 ] Yamaguchi esterification
The amount produced by chemical synthesis is known as the reaction yield. Typically, yields are expressed as a mass in grams (in a laboratory setting) or as a percentage of the total theoretical quantity that could be produced based on the limiting reagent. [2] A side reaction is an
Thus, a stochiometric quantity of AlCl 3 is needed. The complex is destroyed upon aqueous workup to give the desired ketone. For example, the classical synthesis of deoxybenzoin calls for 1.1 equivalents of AlCl 3 with respect to the limiting reagent, phenylacetyl chloride. [14]
The Curtin–Hammett principle is a principle in chemical kinetics proposed by David Yarrow Curtin and Louis Plack Hammett.It states that, for a reaction that has a pair of reactive intermediates or reactants that interconvert rapidly (as is usually the case for conformational isomers), each going irreversibly to a different product, the product ratio will depend both on the difference in ...