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The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
Complete solubility occurs when the solvent and solute have the same valency. [2] A metal is more likely to dissolve a metal of higher valency, than vice versa. [1] [3] [4] The solute and solvent should have similar electronegativity.
In chemistry, solvent effects are the influence of a solvent on chemical reactivity or molecular associations. Solvents can have an effect on solubility, stability and reaction rates and choosing the appropriate solvent allows for thermodynamic and kinetic control over a chemical reaction.
A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another.
In decompression theory, the solubility of gases in liquids is of primary importance, as it is the formation of bubbles from these gases that causes decompression sickness. [4] [5] [6] Solubility of gases in liquids is influenced by three main factors: The nature of the solvent liquid and the solute [7]
The solvation shell number of a dissolved electrolyte can be linked to the statistical component of the activity coefficient of the electrolyte and to the ratio between the apparent molar volume of a dissolved electrolyte in a concentrated solution and the molar volume of the solvent (water): [clarification needed]
The real answer obviously depends on the exact nature of a given solvent and solute, because the exact energetics of the solid and solvated forms. That graph in the Solubility#Factors affecting solubility section is kinda neat! DMacks 06:34, 27 June 2010 (UTC)
However, to minimize the amount of solvent used, the extraction should be completely solubility limited (which will take a very long time). Flow rate must therefore be determined depending on the competing factors of time and solvent costs, and also capital costs of pumps, heaters and heat exchangers.