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Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Metal aqua ions are often involved in the formation of complexes. The reaction may be written as pM x+ (aq) + qL y− → [M p L q] (px-qy)+ In reality this is a substitution reaction in which one or more water molecules from the first hydration shell of the metal ion are replaced by ligands, L. The complex is described as an inner-sphere complex.
In chemistry, metal aquo complexes are coordination compounds containing metal ions with only water as a ligand. These complexes are the predominant species in aqueous solutions of many metal salts , such as metal nitrates , sulfates , and perchlorates .
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron , will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt ...
Solvated electrons are involved in the reaction of alkali metals with water, even though the solvated electron has only a fleeting existence. [10] Below pH = 9.6 the hydrated electron reacts with the hydronium ion giving atomic hydrogen, which in turn can react with the hydrated electron giving hydroxide ion and usual molecular hydrogen H 2. [11]
Aquation is the chemical reaction involving "incorporation of one or more integral molecules of water" with or without displacement of other atoms or groups. [1] The term is typically employed to refer to reactions of metal complexes where an anion is displaced by water.
The alkali metals also react with water to form strongly alkaline hydroxides and thus should be handled with great care. The heavier alkali metals react more vigorously than the lighter ones; for example, when dropped into water, caesium produces a larger explosion than potassium if the same number of moles of each metal is used.
Likewise, the corrosion of most metals by oxygen is accelerated at low pH. Providing the electrons for the above reaction is the oxidation of iron that may be described as follows: Fe → Fe 2+ + 2 e −. The following redox reaction also occurs in the presence of water and is crucial to the formation of rust: 4 Fe 2+ + O 2 → 4 Fe 3+ + 2 O 2−