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The equilibrium moisture content (EMC) of a hygroscopic material surrounded at least partially by air is the moisture content at which the material is neither gaining nor losing moisture. The value of the EMC depends on the material and the relative humidity and temperature of the air with which it is in contact.
The definition of a w is where p is the partial water vapor pressure in equilibrium with the solution, and p* is the (partial) vapor pressure of pure water at the same temperature. An alternate definition can be a w ≡ l w x w {\displaystyle a_{w}\equiv l_{w}x_{w}} where l w is the activity coefficient of water and x w is the mole fraction of ...
Humidity is the concentration of water vapor present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. [2] Humidity indicates the likelihood for precipitation, dew, or fog to be present. Humidity depends on the temperature and pressure of the system of interest.
The relationship between water content and equilibrium relative humidity of a material can be displayed graphically by a curve, the so-called moisture sorption isotherm. For each humidity value, a sorption isotherm indicates the corresponding water content value at a given temperature. If the composition or quality of the material changes, then ...
Equilibrium vapor pressure does not require the condensed phase to be a flat surface; it might consist of tiny droplets possibly containing solutes (impurities), such as a cloud. [ 19 ] [ 18 ] Equilibrium vapor pressure may differ significantly from saturation vapor pressure depending on the size of droplets and presence of other particles ...
In order to flatten the steep learning curve aqion provides an introduction to fundamental water-related topics in form of a "chemical pocket calculator". Second. The program mediates between two terminological concepts: The calculations are performed in the "scientific realm" of thermodynamics (activities, speciation, log K values, ionic ...
Since the relative humidity is above 100%, the droplet will grow until it is in thermodynamic equilibrium. As the droplet grows, it never encounters equilibrium, and thus grows without bound, as long as the level of supersaturation is maintained. However, if the supersaturation is only 0.3%, the drop will only grow until about 0.5 micrometers.
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".