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Titanium is one of the few elements that burns in pure nitrogen gas, reacting at 800 °C (1,470 °F) to form titanium nitride, which causes embrittlement. [29] Because of its high reactivity with oxygen, nitrogen, and many other gases, titanium that is evaporated from filaments is the basis for titanium sublimation pumps , in which titanium ...
A 1948 graduate of MIT, Stanley Abkowitz (1927-2017) was a pioneer in the titanium industry and is credited for the invention of the Ti-6Al-4V during his time at the US Army’s Watertown Arsenal Laboratory in the early 1950s. [4] Titanium/Aluminum/Vanadium alloy was hailed as a major breakthrough with strategic military significance.
Titanium alone is a strong, light metal. It is stronger than common, low-carbon steels, but 45% lighter. It is also twice as strong as weak aluminium alloys but only 60% heavier. Titanium has outstanding corrosion resistance to seawater, and thus is used in propeller shafts, rigging and other parts of boats that are exposed to seawater.
The +4 oxidation state dominates titanium chemistry, [1] but compounds in the +3 oxidation state are also numerous. [2] Commonly, titanium adopts an octahedral coordination geometry in its complexes, [3] [4] but tetrahedral TiCl 4 is a notable exception. Because of its high oxidation state, titanium(IV) compounds exhibit a high degree of ...
The group is also called the titanium group or titanium family after its lightest member. As is typical for early transition metals, zirconium and hafnium have only the group oxidation state of +4 as a major one, and are quite electropositive and have a less rich coordination chemistry.
Molybdenum-based alloys are widely used, because they are cheaper than superior tungsten alloys. The most widely used alloy of molybdenum is the Titanium-Zirconium-Molybdenum alloy TZM, composed of 0.5% titanium and 0.08% of zirconium (with molybdenum being the rest). The alloy exhibits a higher creep resistance and strength at high ...
Molybdenum oxidizes much faster than tungsten and quickly develops a thick oxide layer that does not adhere well, its oxidation should be therefore limited to just yellowish or at most blue-green color. The oxide is volatile and evaporates as a white smoke above 700 °C; excess oxide can be removed by heating in inert gas (argon) at 1000 °C.
The Al and Cr form oxide layers that passivate the surface and protect the superalloy from further oxidation while B and Y are used to improve the adhesion of this oxide scale to the substrate. [4] Cr, Fe, Co, Mo and Re all preferentially partition to the γ matrix while Al, Ti, Nb, Ta, and V preferentially partition to the γ' precipitates and ...