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Sodium thiocyanate (sometimes called sodium sulphocyanide) is the chemical compound with the formula NaSCN. This colorless deliquescent salt is one of the main sources of the thiocyanate anion . As such, it is used as a precursor for the synthesis of pharmaceuticals and other specialty chemicals . [ 2 ]
Thiocyanate is a potent competitive inhibitor of the thyroid sodium-iodide symporter. [13] Iodine is an essential component of thyroxine . Since thiocyanates will decrease iodide transport into the thyroid follicular cell, they will decrease the amount of thyroxine produced by the thyroid gland.
In methyl thiocyanate, N≡C and C−S distances are 116 and 176 pm. By contrast, N=C and C=S distances are 117 and 158 pm in isothiocyanates. [7] Typical bond angles for C−S−C are 100°. [3] By contrast C−N=C in aryl isothiocyanates is 165°. Again, the thiocyanate isomers are quite different with C−S−C angle near 100°.
Protonated molecular hydrogen – H + 3; Trioxidane – H 2 O 3; Water - H 2 O [204] He. Sodium helide – Na 2 He; I ... Sodium thiocyanate – NaSCN; Sodium ...
Ammonium thiocyanate is stable in air; however, upon heating it isomerizes to thiourea: The equilibrium mixtures at 150 °C and 180 °C contain 30.3% and 25.3% (by weight) thiourea, respectively. When heated at 200 °C, the dry powder decomposes to ammonia, hydrogen sulfide, and carbon disulfide, leaving a residue of guanidinium thiocyanate.
Sodium cyanate is isostructural with sodium fulminate, confirming the linear structure of the cyanate ion. [3] It is made industrially by heating a mixture of sodium carbonate and urea. [4] Na 2 CO 3 + 2 OC(NH 2) 2 → 2 NaNCO + CO 2 + 2 NH 3 + H 2 O. A similar reaction is used to make potassium cyanate. Cyanates are produced when cyanides are ...
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Potassium thiocyanate is the chemical compound with the molecular formula KSCN. It is an important salt of the thiocyanate anion , one of the pseudohalides . The compound has a low melting point relative to most other inorganic salts.