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In physics, the thermal de Broglie wavelength (, sometimes also denoted by ) is a measure of the uncertainty in location of a particle of thermodynamic average momentum in an ideal gas. [1] It is roughly the average de Broglie wavelength of particles in an ideal gas at the specified temperature.
The concept that matter behaves like a wave was proposed by French physicist Louis de Broglie (/ d ə ˈ b r ɔɪ /) in 1924, and so matter waves are also known as de Broglie waves. The de Broglie wavelength is the wavelength , λ , associated with a particle with momentum p through the Planck constant , h : λ = h p . {\displaystyle \lambda ...
De Broglie also proposed that the wavelength λ for a moving particle was equal to h/p where p is the particle's momentum. The period (one cycle of the wave) is equal to 1/ f . This precise Compton periodicity of a matter wave is said to be the necessary condition for a clock, with the implication that any such matter particle may be regarded ...
The wavelength associated with a non-relativistic particle is the de Broglie wavelength =, where is the Planck constant and is the momentum of the particle (mass × velocity for slow-moving particles). For example, a sodium atom traveling at about 300 m/s would have a de Broglie wavelength of about 50 picometres.
The wavelength will always be positive because n′ is defined as the lower level and so is less than n.This equation is valid for all hydrogen-like species, i.e. atoms having only a single electron, and the particular case of hydrogen spectral lines is given by Z = 1.
The failure of classical mechanics applied to molecular, atomic, and nuclear systems and smaller induced the need for a new mechanics: quantum mechanics.The mathematical formulation was led by De Broglie, Bohr, Schrödinger, Pauli, and Heisenberg, and others, around the mid-1920s, and at that time was analogous to that of classical mechanics.
All quantities are in Gaussian units except energy and temperature which are in electronvolts.For the sake of simplicity, a single ionic species is assumed. The ion mass is expressed in units of the proton mass, = / and the ion charge in units of the elementary charge, = / (in the case of a fully ionized atom, equals to the respective atomic number).
The de Broglie relation, [10] [11] [12] also known as de Broglie's momentum–wavelength relation, [4] generalizes the Planck relation to matter waves. Louis de Broglie argued that if particles had a wave nature, the relation E = hν would also apply to them, and postulated that particles would have a wavelength equal to λ = h / p .