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In chemistry, a sulfonyl halide consists of a sulfonyl (>S(=O) 2) group singly bonded to a halogen atom. They have the general formula RSO 2 X, where X is a halogen. The stability of sulfonyl halides decreases in the order fluorides > chlorides > bromides > iodides, all four types being well known. The sulfonyl chlorides and fluorides are of ...
Sulfuryl fluoride (also spelled sulphuryl fluoride) is an inorganic compound with the formula SO 2 F 2. It is an easily condensed gas and has properties more similar to sulfur hexafluoride than sulfuryl chloride , being resistant to hydrolysis even up to 150 °C. [ 3 ]
A palladium acetate catalysed reaction described in 1982 used zinc powder with the main intermediate believed to be CF 3 ZnI with Pd(0) is the active catalyst. [ 35 ] [ 36 ] The first copper catalysed coupling was reported in 2009 and based on an iodoarene , a trifluoromethylsilane , copper iodide and 1,10-phenanthroline . [ 37 ]
On heating, zinc nitrate undergoes thermal decomposition to form zinc oxide, nitrogen dioxide and oxygen: 2 Zn(NO 3) 2 → 2 ZnO + 4 NO 2 + 1 O 2. Aqueous zinc nitrate contains aquo complexes [Zn(H 2 O) 6] 2+ and [Zn(H 2 O) 4] 2+. [3] and, thus, this reaction may be better written as the reaction of the aquated ion with hydroxide through ...
Zinc fluoride is an inorganic chemical compound with the chemical formula Zn F 2. It is encountered as the anhydrous form and also as the tetrahydrate, ZnF 2 ·4H 2 O (rhombohedral crystal structure). [2] It has a high melting point and has the rutile structure containing 6 coordinate zinc, which suggests appreciable ionic character in its ...
Trimethylsilyl enol ethers react with NfF in the presence of a substoichiometric fluoride source at 0 °C to ambient temperature to give alkenyl nonaflates in moderate to good yields. Dried tetra-n-butylammonium fluoride was the preferred fluoride source in one study, [6] but CsF has been used in difficult cases with excellent results. [7]
Zinc is a strong reducing agent with a standard redox potential of −0.76 V. Pure zinc tarnishes rapidly in air, rapidly forming a passive layer. The composition of this layer can be complex, but one constituent is probably basic zinc carbonate, Zn 5 (OH) 6 CO 3. [8] The reaction of zinc with water is slowed by this passive layer.
These compounds react readily with nucleophiles like water, alcohols, amines, thiols, and Grignard reagents. If the nucleophile is water the product is a sulfinic acid, if it is an alcohol the product is a sulfinic ester, if it is a primary or secondary amine the product is a sulfinamide, if it is a thiol the product is a thiosulfinate, while if it is a Grignard reagent the product is a sulfoxide.