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The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
There are many varieties of beds: An adjustable bed is a bed that can be adjusted to a number of different positions. Most hospital beds are adjustable, so that a patient can have different parts of their body elevated for medical reasons. Some people have adjustable beds in private homes.
Another structural difference is the sliding back mechanism (sometimes called wall hugger or wall climber) which allows to minimise the gap with the back wall when the bed is uplifted, keeps the bedside table within reach, and enables the partners using the bed (if split) to keep eye contact at all times. In the 90's the sliding back mechanism ...
2,6-Di-tert-butylpyridine, a weak non-nucleophilic base [2] pK a = 3.58 Phosphazene bases , such as t -Bu-P 4 [ 3 ] Non-nucleophilic bases of high strength are usually anions.
Adjustable beds or electric adjustable bed sizes differ from the standard bed size. The length of these beds differ from a standard size due to the nature of the bed needing to bend. So they are 200 cm in length rather than 191 cm. King size and super king size are normally two 75 cm or two 90 cm adjacent beds. [25]
The terms sec and tert are considered obsolete and should only be used for unsubstituted sec-butoxy, sec-butyl [26] [27] or tert-butyl groups. [ 28 ] [ 27 ] There are various spellings such as "sec-butyl", "s-butyl", "sBu" or "bus" which are also considered obsolete.
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