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Calcium hydroxide has a high enough pH to turn the phenolphthalein a vivid purplish-pink color, thus indicating the presence of water. Chemical pulping: Calcium oxide is used to make calcium hydroxide, which is used to regenerate sodium hydroxide from sodium carbonate in the chemical recovery at kraft pulp mills.
The chemistry of calcium is that of a typical heavy alkaline earth metal. For example, calcium spontaneously reacts with water more quickly than magnesium and less quickly than strontium to produce calcium hydroxide and hydrogen gas. It also reacts with the oxygen and nitrogen in air to form a mixture of calcium oxide and calcium nitride. [14]
However, if a metal reacts with steam, like magnesium, metal oxide is produced as a result of metal hydroxides splitting upon heating. [12] The hydroxides of calcium, strontium and barium are only slightly water-soluble but produce sufficient hydroxide ions to make the environment basic, giving a general equation of:
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO 4 and related hydrates. In the form of γ- anhydrite (the anhydrous form), it is used as a desiccant . One particular hydrate is better known as plaster of Paris , and another occurs naturally as the mineral gypsum .
Solid calcium bromide adopts the rutile structure, featuring octahedral Ca 2+ centres bound to six bromide anions, which also bridge to other Ca 2+ centres. When strongly heated in air, calcium bromide reacts with oxygen to produce calcium oxide and bromine: 2 CaBr 2 + O 2 → 2 CaO + 2 Br 2
Calcium peroxide or calcium dioxide is the inorganic compound with the formula CaO 2. It is the peroxide (O 2 2−) salt of Ca 2+. Commercial samples can be yellowish, but the pure compound is white. It is almost insoluble in water. [3]
The reaction of calcium carbide with water, producing acetylene and calcium hydroxide, [5] was discovered by Friedrich Wöhler in 1862. CaC 2 + 2 H 2 O → C 2 H 2 + Ca(OH) 2 . This reaction was the basis of the industrial manufacture of acetylene, and is the major industrial use of calcium carbide.
Other important organic compounds that contain oxygen are: glycerol, formaldehyde, glutaraldehyde, citric acid, acetic anhydride, acetamide, etc. Epoxides are ethers in which the oxygen atom is part of a ring of three atoms. Oxygen reacts spontaneously with many organic compounds at or below room temperature in a process called autoxidation. [7]