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A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The number of molecules arriving at the area on one side of the gas layer, with speed at angle from the normal, in time interval is () / () These molecules made their last collision at y = ± ℓ cos θ {\displaystyle y=\pm \ell \cos \theta } , where ℓ {\displaystyle \ell } is the mean free path .
Initially, there are solute molecules on the left side of a barrier (purple line) and none on the right. The barrier is removed, and the solute diffuses to fill the whole container. Top: A single molecule moves around randomly. Middle: With more molecules, there is a clear trend where the solute fills the container more and more uniformly.
Therefore, the "net" movement of oxygen molecules (the difference between the number of molecules either entering or leaving the cell) is into the cell. In other words, there is a net movement of oxygen molecules down the concentration gradient. In astronomy, atomic diffusion is used to model the stellar atmospheres of chemically peculiar stars.
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate.
One classical thermal escape mechanism is Jeans escape, [1] named after British astronomer Sir James Jeans, who first described this process of atmospheric loss. [2] In a quantity of gas, the average velocity of any one molecule is measured by the gas's temperature, but the velocities of individual molecules change as they collide with one another, gaining and losing kinetic energy.
When a catalyst is involved in the collision between the reactant molecules, less energy is required for the chemical change to take place, and hence more collisions have sufficient energy for the reaction to occur. The reaction rate therefore increases. Collision theory is closely related to chemical kinetics.
Catalysts are substances that make weak bonds with reactants or intermediates and change the pathway (mechanism) of a reaction which in turn increases the speed of a reaction by lowering the activation energy needed for the reaction to take place. A catalyst is not destroyed or changed during a reaction, so it can be used again.