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A polyurethane is typically produced by reacting a polymeric isocyanate with a polyol. [3] Since a polyurethane contains two types of monomers, which polymerize one after the other, they are classed as alternating copolymers. Both the isocyanates and polyols used to make a polyurethane contain two or more functional groups per molecule.
Polyether polyols have numerous uses. [16] [17] As an example, polyurethane foam is a big user of polyether polyols.[18]Polyester polyols can be used to produce rigid foam. [19] [20] They are available in both aromatic and aliphatic versions.
Natural oil polyols, also known as NOPs or biopolyols, are polyols derived from vegetable oils by several different techniques. The primary use for these materials is in the production of polyurethanes .
In polyurethane chemistry, prepolymers and oligomers are frequently produced and then further formulated into CASE applications - Coatings, Adhesives, Sealants, and Elastomers. An isocyanate (usually a diisocyanate) is reacted with a polyol. All types of polyol may in theory be used to produce polyurethane prepolymers.
MDI reacts with polyols in the manufacture of polyurethane. It is the most produced diisocyanate, accounting for 61.3% of the global market in the year 2000 ...
Polyurethane dispersion, or PUD, is understood to be a polyurethane polymer resin dispersed in water, rather than a solvent, although some cosolvent may be used.Its manufacture involves the synthesis of polyurethanes having carboxylic acid functionality or nonionic hydrophiles like PEG (polyethylene glycol) incorporated into, or pendant from, the polymer backbone. [1]
The generalised chemical structure of polyisocyanurate showing the isocyanurate group. The polyols are abbreviated as R-groups.. Polyisocyanurate (/ ˌ p ɒ l ɪ ˌ aɪ s oʊ s aɪ ˈ æ nj ʊər eɪ t /), also referred to as PIR, polyol, or ISO, is a thermoset plastic [1] typically produced as a foam and used as rigid thermal insulation.
Moisture cured polyurethane–urea coatings have been made by reacting 1,2,3-triazole rich polyether polyols with HMDI at NCO/OH eq. ratio of 1.2 to obtain isocyanate-terminated polyurethane prepolymers. The prepolymers were cured under atmospheric moisture to make polyurethane–urea free films. [5]
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