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T is the temperature, T TPW = 273.16 K by the definition of the kelvin at that time; A r (Ar) is the relative atomic mass of argon and M u = 10 −3 kg⋅mol −1 as defined at the time. However, following the 2019 revision of the SI, R now has an exact value defined in terms of other exactly defined physical constants.
The relationship between the two constants is R s = R / m, where m is the molecular mass of the gas. The US Standard Atmosphere (USSA) uses 8.31432 m 3 ·Pa/(mol·K) as the value of R. However, the USSA in 1976 does recognize that this value is not consistent with the values of the Avogadro constant and the Boltzmann constant. [49]
In 1954, the definition of the atmosphere was revised by the 10th General Conference on Weights and Measures [3] to the currently accepted definition: one atmosphere is equal to 101325 pascals. The torr was then redefined as 1 / 760 of one atmosphere. This yields a precise definition that is unambiguous and independent of measurements ...
For instance, if the atmospheric pressure is 100 kPa (15 psi), a gas (such as helium) at 200 kPa (29 psi) (gauge) (300 kPa or 44 psi [absolute]) is 50% denser than the same gas at 100 kPa (15 psi) (gauge) (200 kPa or 29 psi [absolute]). Focusing on gauge values, one might erroneously conclude the first sample had twice the density of the second ...
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
The pascal (Pa) or kilopascal (kPa) as a unit of pressure measurement is widely used throughout the world and has largely replaced the pounds per square inch (psi) unit, except in some countries that still use the imperial measurement system or the US customary system, including the United States.
Atmospheric pressure, also known as air pressure or barometric pressure (after the barometer), is the pressure within the atmosphere of Earth.The standard atmosphere (symbol: atm) is a unit of pressure defined as 101,325 Pa (1,013.25 hPa), which is equivalent to 1,013.25 millibars, [1] 760 mm Hg, 29.9212 inches Hg, or 14.696 psi. [2]
The standard atmosphere was originally defined as the pressure exerted by a 760 mm column of mercury at 0 °C (32 °F) and standard gravity (g n = 9.806 65 m/s 2). [2] It was used as a reference condition for physical and chemical properties, and the definition of the centigrade temperature scale set 100 °C as the boiling point of water at this pressure.