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Nickel nitrate is the inorganic compound Ni(NO 3) 2 or any hydrate thereof. In the hexahydrate, the nitrate anions are not bonded to nickel. Other hydrates have also been reported: Ni(NO 3) 2. 9H 2 O, Ni(NO 3) 2. 4H 2 O, and Ni(NO 3) 2. 2H 2 O. [3] It is prepared by the reaction of nickel oxide with nitric acid: NiO + 2 HNO 3 + 5 H 2 O → Ni ...
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Nickel(II) nitrite is an inorganic compound with the chemical formula Ni(NO 2) 2. [1] Anhydrous nickel nitrite was first discovered in 1961 by Cyril Clifford Addison, who allowed gaseous nickel tetracarbonyl to react with dinitrogen tetroxide , yielding a green smoke.
Nickel terephthalate can be made by a double decomposition of sodium terephthalate and nickel nitrate. Nickel terephthalate precipitates. Its solubility is 0.38 g/100g water at 25 °C. In ammonium hydroxide a violet solution forms. Boiling acetic acid converts the nickel to nickel acetate.
Nickel nitrate commonly crystallises with six water molecules, [1] but can also be anhydrous, or with two, four or nine waters. [11] triphenylphosphine oxide nickel nitrate [(C 6 H 6) 3 PO] 2 Ni(NO 3) 2 is non ionic, with nitrato as a ligand. It can be made from nickel perchlorate. It is yellow and melts at 266 °C. [12]
Bis(2,4-pentanedionato)nickel(II) is prepared by treating nickel nitrate with acetylacetone in the presence of base. The product is the blue-green diaquo complex Ni(CH 3 COCHCOCH 3) 2 (H 2 O) 2. [9] Ni(NO 3) 2 + 2 CH 3 COCH 2 COCH 3 + 2 H 2 O + 2 NaOH → Ni(CH 3 COCHCOCH 3) 2 (H 2 O) 2 + 2 NaNO 3
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By reacting nickel with chalcogens, nickel sulfide, nickel selenide, and nickel telluride are formed. There are numerous sulfides: Ni 1.5 S, Ni 17 S 18 , Ni 3 S 2 ( heazlewoodite ), Ni 3 S 4 ( polydymite ), Ni 9 S 8 ( godlevskite ), NiS ( millerite ) and two other NiS forms, NiS 2 ( vaesite ) in pyrite structure.