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A PV diagram plots the change in pressure P with respect to volume V for some process or processes. Typically in thermodynamics, the set of processes forms a cycle, so that upon completion of the cycle there has been no net change in state of the system; i.e. the device returns to the starting pressure and volume.
English: Active indirect water heater. 1: Municipal water feed 2: Fluid from water storage tank to external (passive) heat source; passive heat source can be the ground (soil or groundwater), sun or air; eg via heat pump, or thermodynamic solar panel 3: Fluid from heat pump, or thermodynamic solar panel to water storage tank 4: Pump, actuator, controller and other parts 5: Water heater 6 ...
The PV diagram is a particularly useful visualization of a quasi-static process, because the area under the curve of a process is the amount of work done by the system during that process. Thus work is considered to be a process variable , as its exact value depends on the particular path taken between the start and end points of the process.
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You are free: to share – to copy, distribute and transmit the work; to remix – to adapt the work; Under the following conditions: attribution – You must give appropriate credit, provide a link to the license, and indicate if changes were made.
PV systems in general operate at lower efficiency as the temperature increases, and in TPV systems, keeping the photovoltaic cool is a significant challenge. [ 7 ] This contrasts with a somewhat related concept, the "thermoradiative" or "negative emission" cells, in which the photodiode is on the hot side of the heat engine.
If at every point in the cycle the system is in thermodynamic equilibrium, the cycle is reversible. Whether carried out reversible or irreversibly, the net entropy change of the system is zero, as entropy is a state function. During a closed cycle, the system returns to its original thermodynamic state of temperature and pressure.
The figure at right shows a block diagram of a generic heat engine, such as the Carnot engine. In the diagram, the "working body" (system), a term introduced by Clausius in 1850, can be any fluid or vapor body through which heat Q can be introduced or transmitted to produce work. Carnot had postulated that the fluid body could be any substance ...
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