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When collision theory is applied to reactions in solution, the solvent cage has an effect on the reactant molecules, as several collisions can take place in a single encounter, which leads to predicted preexponential factors being too large. ρ values greater than unity can be attributed to favorable entropic contributions.
"The Philosophy of Composition" is an 1846 essay written by American writer Edgar Allan Poe that elucidates a theory about how good writers write when they write well. He concludes that length, "unity of effect" and a logical method are important considerations for good writing.
The concept of chemical similarity can be expanded to consider chemical similarity network theory, where descriptive network properties and graph theory can be applied to analyze large chemical space, estimate chemical diversity and predict drug target. Recently, 3D chemical similarity networks based on 3D ligand conformation have also been ...
The unity of science is a thesis in philosophy of science that says that all the sciences form a unified whole. The variants of the thesis can be classified as ontological (giving a unified account of the structure of reality) and/or as epistemic /pragmatic (giving a unified account of how the activities and products of science work). [ 1 ]
Collision theory is a principle of chemistry used to predict the rates of chemical reactions. It states that when suitable particles of the reactant hit each other with the correct orientation, only a certain amount of collisions result in a perceptible or notable change; these successful changes are called successful collisions.
In organic chemistry, steric effects are nearly universal and affect the rates and activation energies of most chemical reactions to varying degrees. In biochemistry, steric effects are often exploited in naturally occurring molecules such as enzymes , where the catalytic site may be buried within a large protein structure.
A harpoon reaction is a type of chemical reaction, first proposed by Michael Polanyi in 1920, [1] [2] whose mechanism (also called the harpooning mechanism) involves two neutral reactants undergoing an electron transfer over a relatively long distance to form ions that then attract each other closer together. [3]
In chemistry, Le Chatelier's principle (pronounced UK: / l ə ʃ æ ˈ t ɛ l j eɪ / or US: / ˈ ʃ ɑː t əl j eɪ /) [1] is a principle used to predict the effect of a change in conditions on chemical equilibrium. [2] Other names include Chatelier's principle, Braun–Le Chatelier principle, Le Chatelier–Braun principle or the equilibrium ...